{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,23]],"date-time":"2026-03-23T17:55:56Z","timestamp":1774288556266,"version":"3.50.1"},"reference-count":50,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T00:00:00Z","timestamp":1731542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["32201509"],"award-info":[{"award-number":["32201509"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,4,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Selective hydrogenation of lignin\u2010derived phenolic compounds is an essential process for developing the sustainable chemical industry and reducing dependence on nonrenewable resources. Herein, a composite C\u2212SiO<jats:sub>2<\/jats:sub> material (DGC) was prepared via the stepwise pyrolysis and steam activation of the distiller\u2032s grains, a fermentation solid waste from the Chinese liquor industry. After Ru loading, Ru\/DGC was used for the catalytic hydrogenation of phenol to cyclohexanol. Steam activation remarkably increased the hydrophilicity and specific surface area of DGC, introducing oxygen\u2010containing functional groups on the surface of DGC, thereby promoting the adsorption of Ru<jats:sup>3+<\/jats:sup> and phenol. Additionally, the large specific surface area facilitated the dispersion of the active metal. Furthermore, the steam activation of DGC promoted the graphitization of the carbon matrix and formed Si\u2212H\/Si\u2212OH bonds on the SiO<jats:sub>2<\/jats:sub> surface. The benzene ring of phenol interacted with the carbon matrix via \u03c0\u2013\u03c0 stacking, and the hydroxyl group of phenol interacted with SiO<jats:sub>2<\/jats:sub> via hydrogen bonding. The synergistic interactions of phenol at the C\u2212SiO<jats:sub>2<\/jats:sub> interface enhanced phenol adsorption to promote the hydrogenation. Consequently, 100\u2009% of phenol was hydrogenated to cyclohexanol at 60\u2009\u00b0C within 30\u2005min. Furthermore, the optimized catalyst exhibited high activity for phenol hydrogenation even after four reuse cycles. The outstanding stability of the catalyst and its requirement for mild reaction conditions favor its large\u2010scale industrial applications.<\/jats:p>","DOI":"10.1002\/cssc.202401910","type":"journal-article","created":{"date-parts":[[2024,10,21]],"date-time":"2024-10-21T04:50:03Z","timestamp":1729486203000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Distillery\u2010Waste\u2010Derived C\u2212SiO<sub>2<\/sub> Catalyst Support Reinforces Phenol Adsorption and Selective Hydrogenation"],"prefix":"10.1002","volume":"18","author":[{"given":"Xiuzhen","family":"Xu","sequence":"first","affiliation":[{"name":"College of Biomass Science and Engineering Sichuan University  Chengdu 610065 China"},{"name":"National Engineering Laboratory for Clean Technology of Leather Manufacture Sichuan University  Chengdu 610065 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weiqin","family":"Feng","sequence":"additional","affiliation":[{"name":"College of Biomass Science and Engineering Sichuan University  Chengdu 610065 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xudong","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Utilization of Woody Oil Resource Hunan Academy of Forestry  Changsha 410004 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8096-4971","authenticated-orcid":false,"given":"Zhicheng","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Biomass Science and Engineering Sichuan University  Chengdu 610065 China"},{"name":"National Engineering Laboratory for Clean Technology of Leather Manufacture Sichuan University  Chengdu 610065 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bi","family":"Shi","sequence":"additional","affiliation":[{"name":"College of Biomass Science and Engineering Sichuan University  Chengdu 610065 China"},{"name":"National Engineering Laboratory for Clean Technology of Leather Manufacture Sichuan University  Chengdu 610065 China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,11,14]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.3390\/en12020233"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1186\/s42825-023-00113-x"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202002063"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1GC04046D"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2024.131278"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201903174"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9GC02762A"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules27051494"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2022.12.020"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202102099"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2024.119928"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2018.08.189"},{"key":"e_1_2_8_13_1","first-page":"933","volume":"30","author":"Wang H.","year":"2009","journal-title":"Chin. J. Catal."},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2017.08.011"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2023.118227"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2021.149880"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.checat.2022.06.001"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.126481"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2014.07.011"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00449-020-02289-6"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1111\/jfpp.15885"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b05848"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.resconrec.2021.105900"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jff.2023.105722"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jaap.2008.12.007"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/jctb.7096"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.163814"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2022.161382"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1186\/s42825-023-00138-2"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-9592(98)00112-5"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2022.133671"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2016.12.012"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2017.02.061"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.125243"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2021.105374"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/s13399-020-00870-3"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1186\/s42825-023-00122-w"},{"key":"e_1_2_8_38_1","first-page":"388","volume":"7","author":"Abdullahi S. A.","year":"2021","journal-title":"Energy Rep."},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0RA07440C"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2019.112313"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2016.01.043"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2020.120267"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201900566"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2021.05.074"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c19119"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA07306H"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.4c02299"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.18323"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00582"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.03.005"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202401910","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T11:12:06Z","timestamp":1760440326000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202401910"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,14]]},"references-count":50,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2025,4,14]]}},"alternative-id":["10.1002\/cssc.202401910"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202401910","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,14]]},"assertion":[{"value":"2024-08-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-14","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401910"}}