{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T21:54:00Z","timestamp":1788299640467,"version":"build-2803163510"},"reference-count":38,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T00:00:00Z","timestamp":1731542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22272083"],"award-info":[{"award-number":["22272083"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,3,15]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Chemical upcycling of plastic wastes into valuable chemicals is a promising strategy for resolving plastic pollution, but economically viable methods currently are still lacking. Here, we report one\u2010pot hydrogenolysis of PET plastic into\n                    <jats:italic>p<\/jats:italic>\n                    \u2010xylene with an excellent yield (99.8\u2009%) over a robust non\u2010precious Cu\u2010based catalyst, CuZn\/Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , in the absence of alcohol solvents. The presence of Zn species promotes the dispersion of Cu\n                    <jats:sup>0<\/jats:sup>\n                    and increases the ratio of Cu\n                    <jats:sup>+<\/jats:sup>\n                    \/Cu\n                    <jats:sup>0<\/jats:sup>\n                    , whereas the synergistic effect of Cu\n                    <jats:sup>0<\/jats:sup>\n                    and Cu\n                    <jats:sup>+<\/jats:sup>\n                    leads to a superior performance in the conversion of PET. The combination of GC\u2010MS,\n                    <jats:sup>13<\/jats:sup>\n                    C CP MAS NMR, 2D\n                    <jats:sup>1<\/jats:sup>\n                    H\u2010\n                    <jats:sup>13<\/jats:sup>\n                    C CP HETCOR NMR spectroscopy and kinetic studies for the first time demonstrates 4\u2010methyl benzyl alcohol as an important reaction intermediate in the hydrogenolysis of PET. Mechanistic studies indicate that the conversion of PET mainly follows a hydrogenolysis process, involving the cleavage of ester bonds to alcohols and the C\u2212O bond cleavage of alcohols to alkanes. This work not only brings new insight for understanding the upgrading pathway of PET, but also provides a guidance for the design of high\u2010performance non\u2010precious catalysts for the chemical upcycling of plastic wastes.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402013","type":"journal-article","created":{"date-parts":[[2024,10,28]],"date-time":"2024-10-28T14:28:13Z","timestamp":1730125693000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["One\u2010pot Hydrogenolysis of Polyethylene Terephthalate (PET) to\n                    <i>p\u2013<\/i>\n                    xylene over CuZn\/Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Catalyst"],"prefix":"10.1002","volume":"18","author":[{"given":"Mengting","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering &amp; National Institute for Advanced Materials Nankai University  Tianjin 300350 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaojing","family":"Huo","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering &amp; National Institute for Advanced Materials Nankai University  Tianjin 300350 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Longqian","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering &amp; National Institute for Advanced Materials Nankai University  Tianjin 300350 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Ji","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis, National Laboratory for Clean Energy Dalian Institute of Chemical Physics, Chinese Academy of Sciences  Zhongshan Road 457 Dalian 116023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tengda","family":"Ding","sequence":"additional","affiliation":[{"name":"College of Chemistry and Environmental Engineering Shenzhen University  Shenzhen 518060 P. R. China."}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guangjin","family":"Hou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Catalysis, National Laboratory for Clean Energy Dalian Institute of Chemical Physics, Chinese Academy of Sciences  Zhongshan Road 457 Dalian 116023 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Song","family":"Song","sequence":"additional","affiliation":[{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin) State Key Laboratory of Chemical Engineering, Haihe Laboratory of Sustainable Chemical Transformations Tianjin Key Laboratory of Applied Catalysis Science and Engineering, School of Chemical Engineering &amp; Technology Tianjin University  Tianjin,300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5752-0662","authenticated-orcid":false,"given":"Weili","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering &amp; National Institute for Advanced Materials Nankai University  Tianjin 300350 P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,14]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201915651"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aar7734"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-09506-1"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aax0587"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aat9669"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC03536J"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2020.115642"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.118110"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b02294"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202000599"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abc5441"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100196"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-020-00519-4"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202310505"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202011063"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9GC00571D"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100956"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202117528"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.123050"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007423"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.202400190"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.procbio.2020.04.001"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abm9257"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2012.10.004"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2021.03.028"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-31078-w"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202117205"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202000547"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2020.06.008"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.118698"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3DT04268E"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(09)60087-5"},{"key":"e_1_2_7_33_1","unstructured":"R. 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