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Here, we developed a large\u2010pore mesoporous carbon with pore sizes centered around 20\u201330\u2005nm using a templated technical lignin. During the soft\u2010templating process, unique cylindrical supramolecular assemblies form from the copolymer template. This peculiar nanostructuring takes place due to the presence of polyethylene glycol (PEG) segments on both the Pluronic\u00ae template and the PEG\u2010grafted lignin derivative (glycol lignin). A large increase in CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake occurs on the resulting large\u2010pore mesoporous carbon at 270\u2005K close to the saturation pressure (3.2\u2005MPa), owing to capillary condensation. This phenomenon enables a CO\n                    <jats:sub>2<\/jats:sub>\n                    \/CH\n                    <jats:sub>4<\/jats:sub>\n                    selectivity (\n                    <jats:italic>S<\/jats:italic>\n                    <jats:sub>CO2\/CH4<\/jats:sub>\n                    , mol\/mol) of 3.7 at 270\u2005K and 3.1\u2005MPa absolute pressure, and a swift pressure swing regeneration process with desorbed CO\n                    <jats:sub>2<\/jats:sub>\n                    per unit pressure far outperforming a benchmark activated carbon (\n                    <jats:italic>i.e<\/jats:italic>\n                    ., notably rapid decrease in the amount of adsorbed CO\n                    <jats:sub>2<\/jats:sub>\n                    with decreasing pressure). We propose large\u2010pore mesoporous carbons as a novel family of CO\n                    <jats:sub>2<\/jats:sub>\n                    capture adsorbents, based on the phase\u2010transition behavior shift of CO\n                    <jats:sub>2<\/jats:sub>\n                    in the nanoconfined environment. This novel material concept may open new horizons for physisorptive CO\n                    <jats:sub>2<\/jats:sub>\n                    separations with energy\u2010efficient regeneration options.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402034","type":"journal-article","created":{"date-parts":[[2025,1,28]],"date-time":"2025-01-28T22:19:08Z","timestamp":1738102748000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Nanoconfinement\u2010Driven Energy\u2010Efficient CO\n                    <sub>2<\/sub>\n                    Capture and Release at High Pressures on a Unique Large\u2010Pore Mesoporous Carbon"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4268-4423","authenticated-orcid":false,"given":"L\u00e1szl\u00f3","family":"Szab\u00f3","sequence":"first","affiliation":[{"name":"Center for Advanced Materials Forestry and Forest Products Research Institute 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