{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T23:16:13Z","timestamp":1790378173121,"version":"4.1.0"},"reference-count":69,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2025,1,10]],"date-time":"2025-01-10T00:00:00Z","timestamp":1736467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004836","name":"Danmarks Frie Forskningsfond","doi-asserted-by":"publisher","award":["9041-00170B"],"award-info":[{"award-number":["9041-00170B"]}],"id":[{"id":"10.13039\/501100004836","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003246","name":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","doi-asserted-by":"publisher","award":["OCENW.KLEIN.283"],"award-info":[{"award-number":["OCENW.KLEIN.283"]}],"id":[{"id":"10.13039\/501100003246","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,5,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    We are facing a world\u2010wide shortage of clean drinking water which will only be further exacerbated by climate change. The development of reliable and affordable methods for water remediation is thus of utmost importance. Chlorine (which forms active hypochlorites in solution) is the most commonly used disinfectant due to its reliability and low cost. One drawback is that it reacts with organic pollutants to generate toxic chlorinated byproducts. To mitigate chlorination in water remediation, we have investigated the use of catalytic amounts of charged water\u2010soluble iron porphyrins. These are known to activate hypochlorite to generate high valent oxoiron species. We studied the depletion of the model micropollutant phenol and the accumulation of chlorinated disinfection byproducts under water remediation conditions, using iron porphyrins [(TMPyP)FeCl]Cl\n                    <jats:sub>4<\/jats:sub>\n                    and (NH\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>4<\/jats:sub>\n                    [(TPPS)FeCl] as catalysts, by membrane inlet mass spectrometry. Despite bearing opposite charges on the meso\u2010substituent, both iron porphyrins suppress the formation of chlorinated disinfection by\u2010products equally well. To gain further insight, spectroscopic studies were performed. These showed the transient formation of Compound II, followed by either regeneration of the iron(III) porphyrin at low NaOCl concentrations, or total decomposition of the porphyrin complex at high NaOCl concentrations. Potential future directions for modifications of porphyrin\u2010based catalysts are discussed.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402171","type":"journal-article","created":{"date-parts":[[2024,12,27]],"date-time":"2024-12-27T07:24:26Z","timestamp":1735284266000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Water\u2010Soluble Iron Porphyrins as Catalysts for Suppressing Chlorinated Disinfection Byproducts in Hypochlorite\u2010Dependent Water Remediation"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6033-8351","authenticated-orcid":false,"given":"Sil\u00e8ne","family":"Engbers","sequence":"first","affiliation":[{"name":"Molecular Inorganic Chemistry Stratingh Institute for Chemistry Faculty of Science and Engineering University of Groningen  Nijenborgh 3 9747 AG Groningen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maja J.","family":"Lind","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Pharmacy University of Southern Denmark  Campusvej 55 Odense M 5320 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2240-1692","authenticated-orcid":false,"given":"Mathias L.","family":"Skavenborg","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Pharmacy University of Southern Denmark  Campusvej 55 Odense M 5320 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1290-597X","authenticated-orcid":false,"given":"Johannes E. 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N.","family":"Klein","sequence":"additional","affiliation":[{"name":"Molecular Inorganic Chemistry Stratingh Institute for Chemistry Faculty of Science and Engineering University of Groningen  Nijenborgh 3 9747 AG Groningen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7462-0884","authenticated-orcid":false,"given":"Frants R.","family":"Lauritsen","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Pharmacy University of Southern Denmark  Campusvej 55 Odense M 5320 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5587-0626","authenticated-orcid":false,"given":"Christine J.","family":"McKenzie","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Pharmacy University of Southern Denmark  Campusvej 55 Odense M 5320 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,1,10]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"WHO UNICEF World Bank. State of the world's drinking water: an urgent call to action to accelerate progress on ensuring safe drinking water for all. Geneva: World Health Organization; 2022; ISBN 978-92-4-006080-7."},{"key":"e_1_2_7_2_1","unstructured":"Progress on household drinking water sanitation and hygiene 2000-2020: five years into the SDGs. Geneva: World Health Organization (WHO) and the United Nations Children's Fund (UNICEF) 2021; ISBN (WHO) 978-92-4-003084-8."},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.3201\/eid2701.190676"},{"key":"e_1_2_7_4_1","unstructured":"Transforming our World: the 2030 Agenda for Sustainable Development; United Nations:2015 A\/RES\/70\/1."},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.3389\/fmicb.2022.991856"},{"key":"e_1_2_7_6_1","doi-asserted-by":"crossref","unstructured":"National Research Council. 1980. Drinking Water and Health : Volume 2. Washington DC: The National Academies Press. https:\/\/doi.org\/10.17226\/1904.","DOI":"10.17226\/1904"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chemosphere.2011.04.009"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/b002977g"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aca.2008.09.042"},{"key":"e_1_2_7_10_1","first-page":"9780875532875","volume-title":"Standard Methods for the Examination of Water and Wastewater, 23rd Edition.","author":"Rice E. W.","year":"2017"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.coesh.2018.12.006"},{"key":"e_1_2_7_12_1","first-page":"117141","volume-title":"Trends Anal. 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Drinking water in Odense Denmark does not contain residual chlorine or halogenated disinfection byproducts it is supplied from groundwater reservoirs and disinfected by ultraviolet irradiation. https:\/\/www.vandcenter.dk\/viden\/drikkevand"},{"key":"e_1_2_7_57_1","unstructured":"The initial exploration of this chemistry can be found in the MSc thesis of M.\u2005J. Lind (ref. 58). It was found that using either the free ligands or replacing iron with redox inactive zinc showed no supression of chlorination."},{"key":"e_1_2_7_58_1","first-page":"76","volume-title":"Master\u2032s Thesis: Water Remediation Using Catalysts in Combination with Hypochlorite.","author":"Lind M. J.","year":"2023"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00207a019"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00236a019"},{"key":"e_1_2_7_61_1","first-page":"549","volume-title":"J. Chem. Soc. Perkin Trans.","author":"Bell S. E. 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For additional details see supporting information."}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202402171","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,11,11]],"date-time":"2025-11-11T09:37:30Z","timestamp":1762853850000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202402171"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,1,10]]},"references-count":69,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2025,5,5]]}},"alternative-id":["10.1002\/cssc.202402171"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202402171","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,1,10]]},"assertion":[{"value":"2024-10-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-01-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202402171"}}