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However, the inherent kinetic inertness and thermodynamic stability of C\u2010C \u03c3 bonds make this process challenging. Herein, we fabricated a glucose\u2010derived defect\u2010rich hierarchical porous carbon as a heterogeneous catalyst for the oxidative cleavage and esterification of C(CO)\u2010C bonds. Systematic investigations revealed that the hierarchical porous structure enhances the adsorption of O\n                    <jats:sub>2<\/jats:sub>\n                    and ketones, thereby boosting the catalytic efficiency of defects. This catalyst exhibits performance comparable to that of the reported nitrogen\u2010doped or metal nanoparticle\u2010supported carbon materials, as well as transition metal\u2010based homogeneous catalytic systems. This work deepens our understanding of the reaction process underlying this transformation and provides insights for designing efficient carbon\u2010based materials for oxidative transformations.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402553","type":"journal-article","created":{"date-parts":[[2024,12,29]],"date-time":"2024-12-29T22:13:41Z","timestamp":1735510421000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Tailoring the Porous Structure of Carbon for Enhanced Oxidative Cleavage and Esterification of C(CO)\u2010C Bonds"],"prefix":"10.1002","volume":"18","author":[{"given":"Chao","family":"Xie","sequence":"first","affiliation":[{"name":"National &amp; Local Joint Engineering Research Center on Biomass Resource Utilization College of Environmental Science and Engineering Nankai University  Tianjin 300350 P. R. 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