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Photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion, inspired by natural photosynthesis, presents a viable approach for transforming CO\n                    <jats:sub>2<\/jats:sub>\n                    into useful C\n                    <jats:sub>1<\/jats:sub>\n                    \u2010C\n                    <jats:sub>3<\/jats:sub>\n                    chemical intermediates for industrial purposes. However, the inherent stability of CO\n                    <jats:sub>2<\/jats:sub>\n                    and the competing hydrogen evolution reaction (HER) introduce significant obstacles. Imidazolium\u2010based ionic liquids can pre\u2010activate CO\n                    <jats:sub>2<\/jats:sub>\n                    , accelerate reaction kinetics, and act as eco\u2010friendly solvents or additives. Systems employing ionic liquids with catalysts, such as homogeneous organocatalysts and heterogeneous materials like Metal\u2010Organic Frameworks (MOFs) and quantum dots, offer potential solutions to these challenges. This review focuses on the role of ionic liquids in both homogeneous and heterogeneous photocatalytic processes, emphasizing their use in CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction and highlighting recent mechanistic insights for imidazolium\u2010based species.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402626","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T08:12:17Z","timestamp":1741680737000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Photocatalytic Carbon Dioxide Reduction with Imidazolium\u2010Based Ionic Liquids"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-3665-3255","authenticated-orcid":false,"given":"Lisa","family":"Eisele","sequence":"first","affiliation":[{"name":"Institute of Applied Synthetic Chemistry TU Wien  Getreidemarkt 9\/163 1060 Wien 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