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Their synthesis via the hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    using solar energy emerges as a promising technology, combining both the utilisation of a renewable primary energy source and the (re)utilisation of a major greenhouse gas. In this context, GaN has attracted a lot of attention in harnessing solar energy to drive chemical transformations. In this work, we study GaN by\n                    <jats:sup>1<\/jats:sup>\n                    H solid\u2010state NMR spectroscopy, revealing the presence of terminal Ga\u2010OH, bridging Ga\u2010NH\u2010Ga, as well as Ga\u2010OH\u2010Ga surface functional groups and combinations thereof. With this knowledge in hand, we make use of surface organometallic chemistry (SOMC) to prepare a Pt\/GaN catalyst with highly dispersed Pt nanoparticles on GaN. Under photothermal conditions using visible light (&gt;320\u2005nm), the synthesised Pt\/GaN promotes the hydrogenation of CO\n                    <jats:sub>2<\/jats:sub>\n                    to C\n                    <jats:sub>2+<\/jats:sub>\n                    products such as acetone, EtOH,\n                    <jats:sup>i<\/jats:sup>\n                    PrOH, and acetic acid in a batch reactor at 60\u2009\u00b0C and 1 bar of pressure, while the pristine GaN counterpart only produces minor amounts of MeOH and acetone. Furthermore, a recycling test was performed to showcase the stability of the catalyst over multiple batch reaction cycles.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402646","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T01:39:58Z","timestamp":1741743598000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Catalytic Photothermal Hydrogenation of Carbon Dioxide to Liquid Fuels using Pt\/GaN Prepared via Surface Organometallic Chemistry"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6594-6441","authenticated-orcid":false,"given":"Hyotaik","family":"Kang","sequence":"first","affiliation":[{"name":"Department of Chemistry FRQNT Centre for Green Chemistry and Catalysis McGill University  801 Sherbrooke Street West Montreal, Quebec H3A 0B8 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Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9660-3890","authenticated-orcid":false,"given":"Christophe","family":"Cop\u00e9ret","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Applied Biosciences ETH Zurich  Vladimir-Prelog-Weg 2 CH-8093 Zurich Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3859-8824","authenticated-orcid":false,"given":"Chao\u2010Jun","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry FRQNT Centre for Green Chemistry and Catalysis McGill University  801 Sherbrooke Street West Montreal, Quebec H3A 0B8 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