{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:39:42Z","timestamp":1786977582293,"version":"build-2736575974"},"reference-count":66,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,3,26]],"date-time":"2025-03-26T00:00:00Z","timestamp":1742947200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22261132512"],"award-info":[{"award-number":["22261132512"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52303265"],"award-info":[{"award-number":["52303265"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["FRF-EYIT-23-02"],"award-info":[{"award-number":["FRF-EYIT-23-02"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["FRF-BR-23-02B"],"award-info":[{"award-number":["FRF-BR-23-02B"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,6,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The emergence of visible\u2010light photocatalytic frameworks provides a sustainable technology for dealing with CO\n                    <jats:sub>2<\/jats:sub>\n                    greenhouse gas. Herein, the solvothermal reaction of copper(I) cyclic trinuclear complex (Cu\u2010CTC) with 2,5\u2010dihydroxyterephthalaldehyde (2,5\u2010DHTA) or 3,3\u2019\u2010dihydroxy\u2010\n                    <jats:sup>[1,1\u2019\u2010biphenyl]<\/jats:sup>\n                    \u20104,4\u2019\u2010dicarbaldehyde (3,3\u2019\u2010DHBDA) led to two crystalline\n                    <jats:bold>hcb<\/jats:bold>\n                    topological copper(I)\u2010organic frameworks USTB\u201048 and USTB\u201049, respectively. The post\u2010cobaltization of 2\u2010(benzylideneamino)phenol units in these two frameworks, providing the active catalytic centers in obtained USTB\u201048(Co) and USTB\u201049(Co) for photocatalysis of CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. The parent frameworks and post\u2010modificated species have been thoroughly characterized through powder X\u2010ray diffraction analysis and various spectroscopies. The combination of trinuclear copper units and single cobalt centers is able to achieve the CO generation rate up to\n                    <jats:italic>ca<\/jats:italic>\n                    . 8451 \u03bcmol\u22c5g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u22c5h\n                    <jats:sup>\u22121<\/jats:sup>\n                    and 96\u2009% selectivity for USTB\u201048(Co).\n                  <\/jats:p>","DOI":"10.1002\/cssc.202402648","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T05:43:23Z","timestamp":1741758203000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Post\u2010Cobaltization of Crystalline Trinuclear Copper Cluster\u2010Based Metal\u2013Organic Frameworks for Photocatalytic CO\n                    <sub>2<\/sub>\n                    Reduction"],"prefix":"10.1002","volume":"18","author":[{"given":"Shuocai","family":"Wang","sequence":"first","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Ding","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucheng","family":"Jin","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziwen","family":"Zhou","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Lu","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Yang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0138-2966","authenticated-orcid":false,"given":"Hailong","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,26]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00412"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60435G"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00373"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014556"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-024-01599-6"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1188566"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202200471"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202002262"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202411118"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c12542"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature23016"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201901997"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13930"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11446"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202311999"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02425"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902218"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE03643A"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2016.10.065"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202319313"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02250"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.08.004"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10350"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c05577"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.121320"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1554-z"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00727A"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00400"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202106259"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad4011"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-023-01334-7"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103525"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00560"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11051"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00011"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102373"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207130"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208791"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-023-1777-y"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00017E"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00299E"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202402208"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115308"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016710"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02997"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09705"},{"key":"e_1_2_7_47_1","first-page":"12777","volume":"11","author":"Duan H.","year":"2023","journal-title":"Chem. A."},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-36779-4"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202307743"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202114244"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c23941"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.07.041"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304861"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-32449-z"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04887"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201601387"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-020-9801-3"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA00154E"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40843-023-2793-3"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09502"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407092"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13817"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302808"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407092"},{"key":"e_1_2_7_65_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202302808"},{"key":"e_1_2_7_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202211482"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202402648","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,22]],"date-time":"2025-10-22T17:39:12Z","timestamp":1761154752000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202402648"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,26]]},"references-count":66,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2025,6,2]]}},"alternative-id":["10.1002\/cssc.202402648"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202402648","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,26]]},"assertion":[{"value":"2024-12-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202402648"}}