{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T16:23:24Z","timestamp":1787675004692,"version":"build-2784847793"},"reference-count":47,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,3,26]],"date-time":"2025-03-26T00:00:00Z","timestamp":1742947200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,6,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Sodium\u2010rich Prussian blue analogs (PBAs) are promising cathode candidates for sodium\u2010ion batteries, offering high crystallinity, excellent electrochemical performance, and low cost. However, traditional hydrothermal synthesis often necessitates acid treatment, which presents a safety risk due to the potential release of toxic hydrogen cyanide (HCN). Inspired by sodium thiosulfate (Na\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    ) as a known cyanide antidote, we developed a novel synthesis method that mitigates the risks of HCN leakage, yields high\u2010crystallinity products with minimal defects while promoting the formation of sodium\u2010rich PBAs in a reducing atmosphere. The resulting PBAs exhibited excellent electrochemical performance, including a high initial coulombic efficiency of 98\u2009%, a stable discharge capacity of 143\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.2\u2005C, and a capacity of 101\u2005mAh\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5\u2005C, while maintaining 84\u2009% of initial capacity over 1000\u2005cycles. These properties are attributed to improved Na content and crystallinity as well as reduced defects and water of PBAs enabled by Na\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/cssc.202500075","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T20:10:35Z","timestamp":1741723835000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Cyanide Antidote inspired Ecofriendly Preparation of Sodium\u2010rich, High\u2010crystallinity Prussian Blue Cathode Materials from a Single\u2010iron Source Method"],"prefix":"10.1002","volume":"18","author":[{"given":"Chengyu","family":"Zhang","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"College of Chemistry and Meterials Science Fujian Normal University  Fuzhou 350007 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"},{"name":"Fujian College University of Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gang","family":"Wang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kai","family":"Zhang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiafan","family":"Zheng","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"College of Chemistry and Meterials Science Fujian Normal University  Fuzhou 350007 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenwu","family":"Fu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanmei","family":"Zhao","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"College of Chemistry and Meterials Science Fujian Normal University  Fuzhou 350007 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junwei","family":"Li","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"College of Chemistry and Meterials Science Fujian Normal University  Fuzhou 350007 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jieyuan","family":"Wang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"College of Chemistry and Meterials Science Fujian Normal University  Fuzhou 350007 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jun","family":"Zheng","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming","family":"Zhang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9740-7848","authenticated-orcid":false,"given":"Zhongrong","family":"Shen","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Key Laboratory of Nanomaterials Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials, Haixi Institutes Chinese Academy of Sciences  Xiamen 361021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,26]]},"reference":[{"key":"e_1_2_9_1_1","volume":"30","author":"Liu Q.","year":"2020","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/sus2.170"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pnsc.2022.12.003"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2023.169886"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214478"},{"key":"e_1_2_9_6_1","volume":"502","author":"Zheng J.","year":"2024","journal-title":"Chem. Eng. J."},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-014-0588-7"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201902013"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2019.135533"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-14444-4"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2020.04.027"},{"key":"e_1_2_9_12_1","volume":"6","author":"Yin J.","year":"2022","journal-title":"Small Methods"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201701715"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c20067"},{"key":"e_1_2_9_15_1","volume":"567","author":"Wu L. L.","year":"2021","journal-title":"Appl. Surf. Sci."},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2019.03.014"},{"key":"e_1_2_9_17_1","volume":"7","author":"Lim C. Q. X.","year":"2020","journal-title":"Adv. Mater. Interfaces"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC06123J"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3EE44004D"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-4509(05)82266-7"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.annemergmed.2016.09.034"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jclepro.2022.135818"},{"key":"e_1_2_9_23_1","volume":"367","author":"Han M.","year":"2024","journal-title":"Chemosphere"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201600991"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2020.126047"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA01209D"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1080\/15563650.2018.1435886"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ssi.2024.116462"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c11169"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202300845"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC06248C"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202300435"},{"key":"e_1_2_9_33_1","volume":"624","author":"Nguyen T. X.","year":"2024","journal-title":"J. Power Sources"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.04.007"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2023.128000"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201801099"},{"key":"e_1_2_9_37_1","volume":"109","author":"Wang Z.","year":"2023","journal-title":"Nano Energy"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.314"},{"key":"e_1_2_9_39_1","volume":"16","author":"Li M.","year":"2023","journal-title":"ChemSusChem"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2022.107708"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202403211"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.05.005"},{"key":"e_1_2_9_43_1","author":"Wang Y.","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-021-01151-8"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c11823"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.084310jes"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-024-01266-1"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202500075","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,22]],"date-time":"2025-10-22T17:37:27Z","timestamp":1761154647000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202500075"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,3,26]]},"references-count":47,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2025,6,2]]}},"alternative-id":["10.1002\/cssc.202500075"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202500075","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,3,26]]},"assertion":[{"value":"2025-01-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-03-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500075"}}