{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T23:54:12Z","timestamp":1789343652742,"version":"build-2803163510"},"reference-count":29,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,4,4]],"date-time":"2025-04-04T00:00:00Z","timestamp":1743724800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["DP220101290"],"award-info":[{"award-number":["DP220101290"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,6,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Visible\u2010light\u2010driven carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) reduction presents a long\u2010term answer to environmental challenges. However, the limited effective optical carriers generated by the limited response dynamics of the existing photocatalyst have severely hindered the development of high efficiency photocatalysts. Here, we report a method of cobalt atoms intercalation in ultrathin BiOBr nanosheets for boosted photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. The experimental results show that there is a strong spatial charge transfer between the intercalated atoms and the two\u2010dimensional material matrix. Cobalt atom intercalation regulates the reaction kinetics of the catalyst, enhances the distribution of photogenerated carriers on the surface of the catalyst, and inhibits the recombination of photogenerated electrons and holes. This 2D material intercalation technique increases the catalyst\u2018s light absorption efficiency while also improving adsorption and desorption of reactants and gas products. Combined with DFT calculations, it is demonstrated that the confinement effect of cobalt atom intercalation introduces additional catalytic active centres and reduces the free energy of the reaction intermediate COOH*. As a result, under 420\u2005nm visible light irradiation in the gas\u2010solid reaction with low water vapor content without any promoters or sacrificial agents, Co\u2010BiOBr achieve a CO formation rate of 36.7\u2005\u03bcmol\u2009g\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , nine times that of the original BiOBr. This work provides guidance for the development of new and efficient photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202500128","type":"journal-article","created":{"date-parts":[[2025,3,12]],"date-time":"2025-03-12T06:35:14Z","timestamp":1741761314000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Atomic Intercalation \u2013 an Approach to Enhance Photogenerated Carrier Dynamics for Efficient Photocatalysis Carbon Dioxide Reduction"],"prefix":"10.1002","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-1434-6437","authenticated-orcid":false,"given":"Dandan","family":"Cui","sequence":"first","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruohang","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhizhen","family":"Ren","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shan","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haifeng","family":"Feng","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyan","family":"Qin","sequence":"additional","affiliation":[{"name":"Intelligent Polymer Research Institute Innovation Campus University of Wollongong  Squires Way North Wollongong NSW 2500 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kunrong","family":"Du","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Du","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weichang","family":"Hao","sequence":"additional","affiliation":[{"name":"School of Physics Beihang University, Haidian District  Beijing 100191 China"},{"name":"Shenzhen Institute of Beihang University  Shenzhen 518000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kang","family":"Xu","sequence":"additional","affiliation":[{"name":"College of Physics and Electronic Information Dezhou University  Dezhou 253023, P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2218-7382","authenticated-orcid":false,"given":"Jun","family":"Chen","sequence":"additional","affiliation":[{"name":"Intelligent Polymer Research Institute Innovation Campus University of Wollongong  Squires Way North Wollongong NSW 2500 Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,4,4]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903879"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2019.06.009"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201704649"},{"key":"e_1_2_9_4_1","author":"Wu J.","year":"2024","journal-title":"Adv. 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