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Among potential products, ethanol stands out as a renewable energy carrier due to its compatibility with existing fuel infrastructure and ability to reduce CO\n                    <jats:sub>2<\/jats:sub>\n                    emissions when integrated into energy systems. Despite the success in converting CO\n                    <jats:sub>2<\/jats:sub>\n                    into C\n                    <jats:sub>1<\/jats:sub>\n                    \u2010Chemicals with high yields, the selective conversion of C\n                    <jats:sub>2+<\/jats:sub>\n                    products, including ethanol, remains a challenge due to the synthetic complexity. This review explores recent advances in CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to ethanol, emphasizing the catalytic performance of noble metals (e.g., Rh, Pd, Au, Ir, and Pt) and non\u2010noble metals (e.g., Co, Cu, and Fe) catalysts. Mechanistic insights into CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion and the role of metal active sites in governing selectivity and by product formation are addressed. A critical balance between reductive and C\u2013C coupling steps for achieving high ethanol yields is highlighted, supported by thermodynamic analyses. Experimental results from batch and continuous\u2010flow reactor systems are discussed. Challenges such as low selectivity and byproduct formation are analyzed alongside strategies to address them, including advanced catalyst designs. This review outlines future research directions for catalyst development and the potential industrial application of CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to ethanol.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202500188","type":"journal-article","created":{"date-parts":[[2025,5,2]],"date-time":"2025-05-02T07:53:39Z","timestamp":1746172419000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["A Review on Catalytic Ethanol Synthesis via Hydrogenation of Carbon Dioxide"],"prefix":"10.1002","volume":"18","author":[{"given":"Abdellah","family":"Ait El Fakir","sequence":"first","affiliation":[{"name":"Institute for Catalysis Hokkaido University  N\u201021, W\u201010 Sapporo 001\u20100021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengfei","family":"Du","sequence":"additional","affiliation":[{"name":"Institute for Catalysis Hokkaido University  N\u201021, W\u201010 Sapporo 001\u20100021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bin","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute for Catalysis Hokkaido University  N\u201021, W\u201010 Sapporo 001\u20100021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nazmul Hasan MD","family":"Dostagir","sequence":"additional","affiliation":[{"name":"Institute for Catalysis Hokkaido University  N\u201021, W\u201010 Sapporo 001\u20100021 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"J\u00f6rg W. 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