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However, the effect of pore sizes\/functionality\/Lewis acid strength on catalytic performance has still not been adequately and systematically investigated and summarized. Herein, a series of isostructural fcu\u2010type metal\u2013organic frameworks (MOFs) are used through a novel strategy to study the effect of subtle changes in pore microenvironment on the catalysis of carbon dioxide (CO<jats:sub>2<\/jats:sub>) cycloaddition at ambient temperature and pressure. The results of systematic experiments indicate that the enlargement of the pore size of MOFs, the access of pore wall functional groups, and the increase of Lewis acid strength of metal nodes can significantly improve the performance of the CO<jats:sub>2<\/jats:sub> cycloaddition reaction. The reaction mechanism catalyzed by fcu\u2010type MOFs is investigated in detail, based on the experimental inferences and periodic calculations of density functional theory. This study provides a reference for designing of high\u2010performance catalysts for CO<jats:sub>2<\/jats:sub> fixation.<\/jats:p>","DOI":"10.1002\/cssc.202500490","type":"journal-article","created":{"date-parts":[[2025,4,12]],"date-time":"2025-04-12T04:50:31Z","timestamp":1744433431000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Tuning the Pore Microenvironment of Metal\u2013Organic Frameworks for Boosting CO<sub>2<\/sub> Fixation"],"prefix":"10.1002","volume":"18","author":[{"given":"Shuo","family":"Liu","sequence":"first","affiliation":[{"name":"College of Chemistry Liaoning University  Shenyang 110036 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry Liaoning University  Shenyang 110036 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