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Conventional Mn\u2010based cathode materials often suffer from the strong Jahn\u2013Teller effect of Mn<jats:sup>III<\/jats:sup>, leading to structural instability and capacity fading. Herein, it is demonstrated that activating charge redistribution between adjacent transition metals in Mn\u2010based Prussian blue analogues, driven by tuning electronic conductivity, plays a crucial role in mitigating the Jahn\u2013Teller effect. X\u2010ray absorption spectroscopy reveals the electronic interaction between Mn and Fe under charge redistribution by demonstrating their complementary redox behavior. Computational analysis attributes this charge redistribution to the structural framework of Prussian blue analogues, where the energy barrier for charge transfer across Fe\uf8ffC\uf8ffN\uf8ffMn bonds is modulated by electrode\u2010level conductivity. This strategy demonstrates the enhanced cycle stability by mitigating Jahn\u2013Teller effect while effectively maintains Mn redox activity beyond the trivalent state. Consequently, this presents a distinct advantage in terms of energy density, and these findings suggest that with optimized electronic conductivity, Mn\u2010based Prussian blue analogues can be positioned as promising cathode materials for next\u2010generation sodium\u2010ion batteries with high energy density and enhanced cycling performance.<\/jats:p>","DOI":"10.1002\/cssc.202500564","type":"journal-article","created":{"date-parts":[[2025,4,9]],"date-time":"2025-04-09T12:13:31Z","timestamp":1744200811000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Highlighting Charge Redistribution Phenomenon in Mn\u2010Based Prussian Blue Analogues for Enhancing Redox Stability"],"prefix":"10.1002","volume":"18","author":[{"given":"Myeongjun","family":"Choi","sequence":"first","affiliation":[{"name":"School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  Ulsan 44919 Republic of 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