{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:53:32Z","timestamp":1760403212147,"version":"build-2065373602"},"reference-count":41,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2025,6,3]],"date-time":"2025-06-03T00:00:00Z","timestamp":1748908800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52276093","52436006"],"award-info":[{"award-number":["52276093","52436006"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,7,17]]},"abstract":"<jats:p>Methanol reforming demonstrates the possibility of realizing hydrogen storage, transport, and on\u2010site supply. Nevertheless, this approach faces limitations due to outlet CO generation and catalyst degradation. This work fabricates a series of CuFeO<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>\u2010based catalytic oxygen carriers (COC) with various Cu\u2010to\u2010Fe ratios for lattice oxygen\u2010induced methanol reforming, which goes through lattice oxygen\u2010induced methanol reforming\u2009\u2009\u2192\u2009\u2009catalytic steam methanol reforming\u2009\u2192\u2009oxidative steam methanol reforming. It is revealed that the lattice oxygen mobility can be tuned by modulating the Cu\u2010to\u2010Fe mole ratios. Of the synthesized COCs, Cu<jats:sub>2<\/jats:sub>Fe<jats:sub>3<\/jats:sub> shows the highest catalytic activity. It is supposed that CuO in COC provides lattice oxygen with catalytically site of Cu<jats:sup>0<\/jats:sup>, while CuFe<jats:sub>5<\/jats:sub>O<jats:sub>8<\/jats:sub> contributes relatively stable Cu<jats:sup>+<\/jats:sup>, synergistically inducing highly efficient oxidative steam reforming of methanol. Specifically, a H<jats:sub>2<\/jats:sub> production rate of 93.9\u2009mmol\u00b7H<jats:sub>2<\/jats:sub>\u00b7h<jats:sup>\u22121<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>\u00b7COC\u00b7at 220\u2009\u00b0C is achieved with relatively stable redox looping within 20 cycles. The in\u2009situ diffuse reflectance infrared Fourier transform spectroscopy results indicate that the bridged formate species is identified as the primary intermediate under lattice oxygen\u2010induced conditions, and the reaction pathway is anticipated to be CH<jats:sub>3<\/jats:sub>OH*\u2009\u2192\u2009CH<jats:sub>3<\/jats:sub>O*\u2009\u2192\u2009CH<jats:sub>2<\/jats:sub>O*\u2009\u2192\u2009HCOO*\u2009\u2192\u2009H<jats:sub>2<\/jats:sub> + CO<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/cssc.202500599","type":"journal-article","created":{"date-parts":[[2025,5,19]],"date-time":"2025-05-19T05:47:06Z","timestamp":1747633626000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring CuFeO<sub><i>x<\/i><\/sub>\u2010Based Catalytic Oxygen Carrier for Lattice Oxygen\u2010Induced Oxidative Steam Reforming of Methanol"],"prefix":"10.1002","volume":"18","author":[{"given":"Feng","family":"Tan","sequence":"first","affiliation":[{"name":"Hunan Engineering Research Centre of Clean and Low\u2010Carbon Energy Technology School of Energy Science and Engineering Central South University  Changsha 410083 P. 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