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The efficient, affordable, and earth\u2010abundant electrocatalysts like 3D copper foam (CuF) provide ideal porous structures for rapid ion transport during water electrolysis. In this study, a bimetallic foam architecture (CuF@Ni) is fabricated by electrodeposition of Ni on CuF. This structure acts as both conductive support and active catalyst during the water electrolysis process. The synthesized CuF@Ni demonstrated superior hydrogen evolution reaction (HER) activity with an overpotential of 0.18\u2009V at 50\u2009mA\u2009cm<jats:sup>\u22122<\/jats:sup>, while the methanol oxidation reaction (MOR) overpotential exhibits 0.14\u2009V at 50\u2009mA\u2009cm<jats:sup>\u22122<\/jats:sup> current density. CuF@Ni electrocatalytic electrode achieved a Faradaic efficiency \u2248100% during 150\u2009C charge transfer. In a co\u2010generation system, the onset potential is observed as lower 0.4\u2009V, and CuF@Ni required only 0.92\u2009V to sustain the current density of 50 mA cm<jats:sup>\u22122<\/jats:sup>, demonstrating significant energy savings. Furthermore, this device consumes less power than theoretical water electrolysis under higher current density. The electrochemical stability of 100 h and 120 h achieved for HER and MOR, respectively, confirmed minimal degradation under the harsh conditions. 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