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Here, it is shown that biobased poly(dodecylene 2,5\u2010furanoate) (PDDF), synthesized via both step\u2010growth polycondensation and chain\u2010growth ring\u2010opening polymerization methods, exhibits advantages not only in gas barrier properties but also in EoL options due to its biodegradability and closed\u2010loop chemical circularity. Specifically, PDDF displays significantly lower oxygen and carbon dioxide permeability than commercial poly(butylene adipate<jats:italic>\u2010co<\/jats:italic>\u2010terephthalate) (PBAT) and linear low\u2010density polyethylene , alongside a markedly higher modulus (by \u22483\u2009\u00d7) and reduced water vapor transmission rate compared to PBAT. This superior performance is attributed to the inherently rigid, polar, H\u2010bonding furan rings that enhance chain interaction, packing and crystallinity and thus reduce free volume impeding gas diffusion, while the long hydrophobic dodecylene segments inhibit water permeation. 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These superior barrier properties, coupled with biodegradation and closed\u2010loop circularity, highlight the potential of the biobased PDDF as a more sustainable alternative for packaging.<\/jats:p>","DOI":"10.1002\/cssc.202501080","type":"journal-article","created":{"date-parts":[[2025,6,24]],"date-time":"2025-06-24T00:14:22Z","timestamp":1750724062000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Biobased Poly(dodecylene Furanoate) with Inherent Advantages in Performance and Circularity"],"prefix":"10.1002","volume":"18","author":[{"given":"Hesham","family":"Aboukeila","sequence":"first","affiliation":[{"name":"School of Sustainable Chemical, Biological and Materials Engineering University of Oklahoma  Norman OK 73019 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eswara Rao","family":"Chokkapu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado 80523\u20101872 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang\u2010Fei","family":"Tu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado 80523\u20101872 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Onkar","family":"Singh","sequence":"additional","affiliation":[{"name":"School of Sustainable Chemical, Biological and Materials Engineering University of Oklahoma  Norman OK 73019 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wilfred T.","family":"Diment","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado 80523\u20101872 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu","family":"Xu","sequence":"additional","affiliation":[{"name":"Department of Sustainable Materials and Processes Applied Materials Division Argonne National Laboratory  Lemont IL 60439 United States"},{"name":"Northwestern Argonne Institute of Science &amp; Engineering  Evanston IL 60208 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meltem","family":"Urgun\u2010Demirtas","sequence":"additional","affiliation":[{"name":"Department of Sustainable Materials and Processes Applied Materials Division Argonne National Laboratory  Lemont IL 60439 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"John","family":"Klier","sequence":"additional","affiliation":[{"name":"School of Sustainable Chemical, Biological and Materials Engineering University of Oklahoma  Norman OK 73019 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"George W.","family":"Huber","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering University of Wisconsin \u2010 Madison  1415 Engineering Drive Madison Wisconsin 53706 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4975-8029","authenticated-orcid":false,"given":"Brian P.","family":"Grady","sequence":"additional","affiliation":[{"name":"School of Sustainable Chemical, Biological and Materials Engineering University of Oklahoma  Norman OK 73019 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7512-3484","authenticated-orcid":false,"given":"Eugene Y.\u2010X.","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado 80523\u20101872 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,7,10]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/pola.27730"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/502615a"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.164629"},{"key":"e_1_2_8_5_1","unstructured":"Ruiz A.25 Plastic Waste Statistics That Will Shock You. 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