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The key advantage of this approach lies in the use of recently developed three\u2010component, double\u2010acidic deep eutectic solvents (DESs), designed by our research team, which act as triple\u2010active media\u2014simultaneously serving as solvents, reagents, and catalysts. The reaction setup is straightforward and can be carried out under conventional or dielectric heating, typically providing the desired products in good to excellent yields. For terminal alkynes, microwave heating further enhances the sustainability of the process by a significant reduction of reaction times. 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