{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T16:11:26Z","timestamp":1790439086156,"version":"4.1.0"},"reference-count":60,"publisher":"Wiley","issue":"22","license":[{"start":{"date-parts":[[2025,10,7]],"date-time":"2025-10-07T00:00:00Z","timestamp":1759795200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2025,11,24]]},"abstract":"<jats:p>\n                    An environmentally benign, transition\u2010metal\u2010free catalytic method has been developed for the synthesis of important classes of bioactive N\u2010heterocycles, including quinoline, quinazoline, and quinazolinone under exposure of blue light. In this method, benzylic alcohol derivatives are catalytically dehydrogenated to the corresponding aldehydes by a redox\u2010active molecule known as bis(arylimino)acenaphthene (Ar\u2010BIAN) under exposure of blue light, and subsequently they react with ketones, nitriles, and amide partners. By using aerial\u2010O\n                    <jats:sub>2<\/jats:sub>\n                    as a terminal oxidant, a variety of heavily functionalized N\u2010heterocycles have been successfully synthesized with good to excellent yields across 59 examples. The organocatalyst used in this method demonstrates high compatibility and selectivity compared to previously reported transition metal catalysts. A plausible mechanistic path for the current protocol by combining structural, electrochemical, and photophysical properties, spectroscopic results, various control experiments, and detailed theoretical calculations is proposed.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202501498","type":"journal-article","created":{"date-parts":[[2025,10,8]],"date-time":"2025-10-08T00:19:21Z","timestamp":1759882761000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Redox\u2010Active Bis(arylimino)acenaphthene\u2010Catalyzed Dehydrogenative Aerial Functionalization of Alcohols to N\u2010Heterocycles Under Exposure of Visible Light"],"prefix":"10.1002","volume":"18","author":[{"given":"Krishnendu","family":"Paramanik","sequence":"first","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling 734013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nilaj","family":"Bandopadhyay","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling 734013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agnishwar","family":"Mangal","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling 734013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sourabh","family":"Pal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Jadavpur University  188 Raja Subodh Chandra Mallick Rd, Jadavpur Kolkata 700032 West Bengal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Suraj Kumar","family":"Agrawalla","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research  Bhubaneswar Orissa 751005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chandra Shekhar","family":"Purohit","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research  Bhubaneswar Orissa 751005 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5447-9729","authenticated-orcid":false,"given":"Bhaskar","family":"Biswas","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling 734013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8846-8200","authenticated-orcid":false,"given":"Jasimuddin","family":"Ahmed","sequence":"additional","affiliation":[{"name":"Department of Chemistry Jadavpur University  188 Raja Subodh Chandra Mallick Rd, Jadavpur Kolkata 700032 West Bengal"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0036-0244","authenticated-orcid":false,"given":"Hari Sankar","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of North Bengal  Darjeeling 734013 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,10,7]]},"reference":[{"key":"e_1_2_11_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b819925f"},{"key":"e_1_2_11_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b104971m"},{"key":"e_1_2_11_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm900003c"},{"key":"e_1_2_11_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ejmech.2014.10.084"},{"key":"e_1_2_11_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm501100b"},{"key":"e_1_2_11_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b06746"},{"key":"e_1_2_11_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmedchemlett.5b00286"},{"key":"e_1_2_11_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2007.10.027"},{"key":"e_1_2_11_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0223-5234(00)01175-2"},{"key":"e_1_2_11_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2008.06.037"},{"key":"e_1_2_11_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2006.02.020"},{"key":"e_1_2_11_13_1","doi-asserted-by":"publisher","DOI":"10.1128\/AAC.48.11.4154-4162.2004"},{"key":"e_1_2_11_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0014-827X(01)01134-X"},{"key":"e_1_2_11_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CY00342K"},{"key":"e_1_2_11_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo201054k"},{"key":"e_1_2_11_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.6b01518"},{"key":"e_1_2_11_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo301282n"},{"key":"e_1_2_11_19_1","first-page":"277","volume":"5","author":"Chen B. 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