{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T22:28:59Z","timestamp":1790202539269,"version":"4.1.0"},"reference-count":59,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T00:00:00Z","timestamp":1771372800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T00:00:00Z","timestamp":1771372800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,2,25]]},"abstract":"<jats:p>\n                    A major obstacle to the commercial application of metal\u2010organic frameworks (MOFs) is that their powder form hinders scalable membrane fabrication and significantly compromises stability under humid conditions. To address these limitations, this study presents a novel, humidity\u2010resistant zeolitic imidazolate framework ZIF\u201067\/alumina composite membrane (MMF) that combines visible\u2010light volatile organic compound (VOC) degradation and CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption in a single, scalable platform. Using an in situ self\u2010conversion strategy, ZIF\u201067 crystals were directly anchored onto porous alumina, providing strong interfacial bonding, mechanical durability, and efficient mass transport. The MMF exhibited excellent toluene adsorption, as described by the Langmuir model, and achieved 96.4% photocatalytic degradation under visible light. Radical\u2010trapping and Electron spin resonance (ESR) studies confirmed superoxide anions (\n                    <jats:sup>.<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) as the dominant active species. The photocatalytic performance declined at 70\u201380% relative humidity\u00a0(RH). To overcome this, ultrathin hydrophobic polysiloxane and perfluorinated polymer coatings minimized water uptake and maintained &gt;92% photocatalytic activity, as supported by water vapor isotherms. Beyond VOC abatement, the MMFs demonstrated promising CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption predominantly by physisorption with higher uptake at low temperature and high pressure, attributed to enhanced pore filling and van der Waals interactions with nitrogen\u2010rich active sites. This work establishes a scalable strategy for MOF\u2010based membranes for simultaneous VOC abatement and CO\n                    <jats:sub>2<\/jats:sub>\n                    capture, offering a promising pathway for air\u2010purification technologies.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202501998","type":"journal-article","created":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T04:11:16Z","timestamp":1771474276000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Hydrophobic Polymer\u2010Coated and Uncoated ZIF\u201067\/Alumina Membrane for Volatile Organic Compound Degradation and CO\n                    <sub>2<\/sub>\n                    Adsorption Capture"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6043-1660","authenticated-orcid":false,"given":"Vijaya Rohini","family":"Parasuraman","sequence":"first","affiliation":[{"name":"Department of 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Uk","family":"Han","sequence":"additional","affiliation":[{"name":"Department of Environmental Resources Research National Institute of Environmental Research (NIER)  Incheon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2937-7947","authenticated-orcid":false,"given":"Seungdo","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Environmental Sciences and Biotechnology Hallym University  Chuncheon Republic of Korea"},{"name":"Research center for Climate Change and Energy (RCCCE) Hallym University  Chuncheon Republic of Korea"},{"name":"Nano\u2010InnoTek Corporation  123, Digital\u2010ro 26\u2010gil, Guro\u2010gu Seoul Republic of Korea"},{"name":"Cait Engineering  Chuncheon Republic of 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