{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,11]],"date-time":"2026-07-11T04:28:26Z","timestamp":1783744106170,"version":"3.55.0"},"reference-count":57,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T00:00:00Z","timestamp":1770768000000},"content-version":"vor","delay-in-days":10,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,1]],"date-time":"2026-02-01T00:00:00Z","timestamp":1769904000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100014188","name":"Ministry of Science and ICT, South Korea","doi-asserted-by":"publisher","award":["2022M3J3A1046019"],"award-info":[{"award-number":["2022M3J3A1046019"]}],"id":[{"id":"10.13039\/501100014188","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,2]]},"abstract":"<jats:p>\n                    Polyurethane (PU) adhesives are extensively employed in flexible packaging owing to their strong adhesion and excellent wettability. However, most conventional PU adhesives are petroleum\u2010based, which has driven growing interest in biobased alternatives. In this article, we synthesized biobased PU adhesives for flexible packaging applications using 2,5\u2010furandicarboxylic acid (FDCA) and carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ). FDCA\u2010based polyols (FPs) (2500\u20133500\u2009g\u2009mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with processable viscosities were prepared from FDCA, succinic acid, and 1,3\u2010propanediol. To further enhance adhesion by increasing hydrogen\u2010bond density, the diol and triol containing urethane moieties were synthesized via CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010utilization technology. In T\u2010peel tests, the adhesives crosslinked with CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based triols exhibited the highest adhesion strength (986 gf\/25\u2009mm) and were compared with those crosslinked using petroleum\u2010derived trimethylolpropane (TMP). The prepared adhesives exhibited low glass transition temperature (from \u221228\u2009 to \u221218\u00b0C), ensuring flexibility at room temperature. In addition, the synthesized adhesives could be degraded through base\u2010catalyzed transesterification in ethanol\/ethyl acetate, enabling clean substrate recovery. These sustainable FDCA\/CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based PU adhesives demonstrate strong potential as alternatives to petroleum\u2010derived adhesives for flexible packaging.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502079","type":"journal-article","created":{"date-parts":[[2026,2,11]],"date-time":"2026-02-11T12:19:06Z","timestamp":1770812346000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Chemically Degradable Carbon Dioxide\u2010Incorporated Polyurethane From Biomass\u2010Derived Polyester Polyols as Sustainable Adhesives"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-0910-1955","authenticated-orcid":false,"given":"Yongseok","family":"Jeong","sequence":"first","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiwon","family":"Jang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujin","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhyeon","family":"Choi","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Kyung Hee University  Yongin Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Okbi","family":"Hong","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoon Kee","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jong Doo","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemistry Sungkyunkwan University  Suwon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jaehyun","family":"Lee","sequence":"additional","affiliation":[{"name":"Kangnam Chemical Co., Ltd.  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