{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T21:29:40Z","timestamp":1792618180143,"version":"4.5.0"},"reference-count":40,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,2,22]],"date-time":"2026-02-22T00:00:00Z","timestamp":1771718400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,22]],"date-time":"2026-02-22T00:00:00Z","timestamp":1771718400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,2,25]]},"abstract":"<jats:p>\n                    The extreme atmospheric persistence of sulfur hexafluoride (SF\n                    <jats:sub>6<\/jats:sub>\n                    ), coupled with its high global warming potential, necessitates effective degradation strategies. Herein, we report a reduction\u2010precipitation platform that simultaneously achieves SF\n                    <jats:sub>6<\/jats:sub>\n                    defluorination and in\u2009situ fluoride immobilization. Hydrated electrons () generated via photoreduction drive the cleavage of S\uf8ffF bonds, achieving enhanced SF\n                    <jats:sub>6<\/jats:sub>\n                    degradation. Crucially, in\u2009situ precipitation with calcium salts directly converts the released fluoride ions into fluorite (CaF\n                    <jats:sub>2<\/jats:sub>\n                    ), eliminating secondary pollution. XRD analysis confirmed complete phase transformation to pure CaF\n                    <jats:sub>2<\/jats:sub>\n                    within 24\u2009h using either Ca(OH)\n                    <jats:sub>2<\/jats:sub>\n                    or CaCl\n                    <jats:sub>2<\/jats:sub>\n                    as the calcium source, with fluoride mineralization efficiency exceeding 98%. This integrated approach of reduction and mineralization offers a new solution for managing SF\n                    <jats:sub>6<\/jats:sub>\n                    and may offer insights for the degradation of other fluorinated greenhouse gases.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502105","type":"journal-article","created":{"date-parts":[[2026,2,23]],"date-time":"2026-02-23T07:36:54Z","timestamp":1771832214000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Hydrated Electron\u2010Driven Defluorination Coupled With In\u2009Situ Mineralization: An Integrated Approach for SF\n                    <sub>6<\/sub>\n                    Degradation and Fluoride Immobilization"],"prefix":"10.1002","volume":"19","author":[{"given":"Xinhua","family":"He","sequence":"first","affiliation":[{"name":"Shaoxing Research Institute of Renewable Energy and Molecular Engineering Shanghai Jiao Tong University  Shaoxing 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