{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:39:42Z","timestamp":1786977582508,"version":"build-2736575974"},"reference-count":75,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2026,1,27]],"date-time":"2026-01-27T00:00:00Z","timestamp":1769472000000},"content-version":"vor","delay-in-days":26,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,1,1]],"date-time":"2026-01-01T00:00:00Z","timestamp":1767225600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,1]]},"abstract":"<jats:p>\n                    This study explores the impact of (i) different installation modes of the molecular rhenium catalyst\n                    <jats:bold>Re<\/jats:bold>\n                    within the PCN\u2010777 metal\u2013organic framework (MOF) and (ii) catalyst loading on the resulting catalytic performance and recyclability of the different hybrid materials in the photocatalytic reduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to CO. Through systematic investigation, we demonstrate that a robust coordination linkage between a zirconium node of the framework and the catalyst, obtained via solvent\u2010assisted ligand incorporation (SALI), minimizes rhenium leaching. In contrast, physical entrapment and electrostatic anchoring methods result in significant rhenium leaching after installation. Additionally, we reveal how the installation mode influences the electronic properties of the catalyst, which allows us to tune the catalytic activity. Furthermore, based on these results, we determine the optimal loading and concentration of\n                    <jats:bold>Re<\/jats:bold>\n                    within the MOF matrix for photocatalytic CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502216","type":"journal-article","created":{"date-parts":[[2026,1,27]],"date-time":"2026-01-27T15:52:57Z","timestamp":1769529177000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Photo\u2010Driven CO\n                    <sub>2<\/sub>\n                    Reduction With a Heterogenized Re Catalyst in the Metal\u2013Organic Framework PCN\u2010777: Effects of Catalyst Loading and Anchoring Strategy on Catalysis"],"prefix":"10.1002","volume":"19","author":[{"given":"Wojciech G.","family":"Sikorski","sequence":"first","affiliation":[{"name":"Homogeneous, Supramolecular and Bioinspired Catalysis Group van \u2018t Hoff Institute for Molecular Sciences Faculty of Science University of Amsterdam  Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martijn J.","family":"Mekkering","sequence":"additional","affiliation":[{"name":"Heterogeneous Catalysis and Sustainable Chemistry Group van \u2018t Hoff Institute for Molecular Sciences Faculty of Science University of Amsterdam  Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arno","family":"van der Weijden","sequence":"additional","affiliation":[{"name":"Self Organizing Matter Group AMOLF Amsterdam  Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefania","family":"Tanase","sequence":"additional","affiliation":[{"name":"Functional Materials Group van \u2018t Hoff Institute for Molecular Sciences Faculty of Science University of Amsterdam  Amsterdam The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Joost N. 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