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However, its conventional production through the energy\u2010intensive Haber\u2013Bosch process results in significant carbon dioxide emissions. Here, we report an eco\u2010friendly solid\u2010state synthesis of bismuth vanadium oxide supported on treated carbon black (Bi\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>21<\/jats:sub>\n                    @CB), denoted as BV64@CB, as an efficient electrocatalyst for the nitrogen reduction reaction (NRR). This electrocatalyst exhibits exceptional activity owing to its unique coordination environment, which effectively sustains electron deficiencies. In this system, vanadium (V\n                    <jats:sup>5+<\/jats:sup>\n                    ) active sites facilitate nitrogen (N\n                    <jats:sub>2<\/jats:sub>\n                    ) adsorption, while bismuth (Bi\n                    <jats:sup>3+<\/jats:sup>\n                    ) promotes the hydrogenation of adsorbed N\n                    <jats:sub>2<\/jats:sub>\n                    , leading to the formation of\n                    <jats:sup>*<\/jats:sup>\n                    NNH intermediates on the BV64@CB surface. The cooperation between vanadium and bismuth enhances NRR efficiency, thereby promoting NH\n                    <jats:sub>3<\/jats:sub>\n                    synthesis via the distal associative pathway. These mechanistic insights are supported by in situ X\u2010ray absorption spectroscopy and Raman analyses. The BV64@CB electrocatalyst exhibits an impressive average NH\n                    <jats:sub>3<\/jats:sub>\n                    yield rate of 370.1\u2009\u03bcg\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u2009mg\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a Faradaic efficiency of 90.94% at \u22120.4\u2009V versus the reversible hydrogen electrode in a 0.2\u2009M Li\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>4<\/jats:sub>\n                    electrolyte (pH 5). This performance surpasses that of other bimetallic oxide electrocatalysts, underscoring its potential as an efficient and sustainable candidate for NH\n                    <jats:sub>3<\/jats:sub>\n                    synthesis.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502368","type":"journal-article","created":{"date-parts":[[2026,3,17]],"date-time":"2026-03-17T03:12:05Z","timestamp":1773717125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Electron\u2010Deficient Bimetallic Oxide Electrocatalyst for High\u2010Efficiency Ammonia Synthesis Under Ambient Conditions"],"prefix":"10.1002","volume":"19","author":[{"given":"Baru Debtera","family":"Bejena","sequence":"first","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Department of Chemical Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chia\u2010Yu","family":"Chang","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology  Taipei Taiwan"},{"name":"Sustainable Electrochemical Energy Development (SEED) Center National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Endalkachew Asefa","family":"Moges","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Graduate Institute of Applied Science and Technology National Taiwan University of Science and Technology  Taipei Taiwan"},{"name":"Sustainable Electrochemical Energy Development (SEED) Center National Taiwan University of Science and Technology  Taipei 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Barasa","family":"Guta","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Department of Chemical Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Habib Gemechu","family":"Edao","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Department of Chemical Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kirubel Teshome","family":"Tadele","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Department of Chemical Engineering National Taiwan University of Science and Technology  Taipei Taiwan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun\u2010Chi","family":"Chang","sequence":"additional","affiliation":[{"name":"Nano\u2010Electrochemistry Laboratory Graduate Institute of Applied 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