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In this work, Prussian blue analogs\u2010derived air\u2010stable Cu\n \n x<\/jats:sub>\n <\/jats:italic>\n Ni\n \n y<\/jats:sub>\n <\/jats:italic>\n @NC\/SiO\n 2<\/jats:sub>\n catalysts have been synthesized by a facile precipitation and thermal decomposition method. The optimized Cu\n 1<\/jats:sub>\n Ni\n 6<\/jats:sub>\n @NC\/SiO\n 2<\/jats:sub>\n exhibits the best hydrogen production performance at room temperature, being 5 times more active than Cu\n 1<\/jats:sub>\n Ni\n 6<\/jats:sub>\n @NC and superior to other Cu\n \n x<\/jats:sub>\n <\/jats:italic>\n Ni\n \n y<\/jats:sub>\n <\/jats:italic>\n @NC\/SiO\n 2<\/jats:sub>\n catalysts. Beyond the reactivity, Cu\n 1<\/jats:sub>\n Ni\n 6<\/jats:sub>\n @NC\/SiO\n 2<\/jats:sub>\n exhibits outstanding durability and antioxidant properties, maintaining its catalytic activity unchanged even after 6\u2009months of air exposure. Characterization tools indicated that the enhanced performance and durability of the Cu\n 1<\/jats:sub>\n Ni\n 6<\/jats:sub>\n @NC\/SiO\n 2<\/jats:sub>\n catalyst originated from a combination of the synergistic effect of Ni\u2013Cu alloying and the core\u2013shell structure. Moreover, Cu\n 1<\/jats:sub>\n Ni\n 6<\/jats:sub>\n @NC\/SiO\n 2<\/jats:sub>\n also exhibits high efficiency and excellent recyclability toward the hydrogenation of adiponitrile and 2\u2010methylglutaronitrile at ambient conditions on coupling with AB dehydrogenation. This research not only provides a simple strategy for the construction of air\u2010stable non\u2010noble metal catalysts for AB hydrolysis, but also offers a promising way for the design of heterogeneous non\u2010noble metal catalysts with excellent oxygen resistance for industrial applications.\n <\/jats:p>","DOI":"10.1002\/cssc.202502449","type":"journal-article","created":{"date-parts":[[2026,2,3]],"date-time":"2026-02-03T03:41:37Z","timestamp":1770090097000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Bimetallic CuNi@NC\/SiO\n 2<\/sub>\n as Air\u2010Stable and Efficient Catalysts for the Hydrolysis of Ammonia Borane"],"prefix":"10.1002","volume":"19","author":[{"given":"Houyu","family":"Tao","sequence":"first","affiliation":[{"name":"College of Chemistry Chemical Engineering and Materials Science Collaborative Innovation Center of Suzhou Nano Science and Technology Soochow University Suzhou 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