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Herein, we have developed a unique polyvinyl chloride (PVC)\u2010derived polymeric host material (named as XC); results show that XC host is capable of achieving strong chemical\/physical confinement to the encapsulated sulfur and lithium polysulfide (LiPS) intermediates, thus significantly reducing the shuttling effect and improving the battery cycle life to above 500 cycles with only 9.3% capacity loss (74.4% after 1000 cycles). While with increased S loading of 6.2\u2009mg\u2010S\/cm\n                    <jats:sup>2<\/jats:sup>\n                    and electrolyte\u2010to\u2010sulfur ratio of 6\u2009\u03bcL\/mg\u2010S, the XC\/S28 composite comprising 20% XC and 80% S maintains 67.5% of its capacity at the 200\n                    <jats:sup>th<\/jats:sup>\n                    cycle. Apart from the chemical immobilization of short\u2010chain S\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    (\n                    <jats:italic>x<\/jats:italic>\n                    \u2009=\u20092\u22124) in micropores or organic skeletons, the use of XC as a polymeric encapsulant still maintains the solid\u2013liquid\u2013solid conversion in highly solvating electrolytes, guaranteeing high discharge voltage and energy while significantly extending cycle life.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502585","type":"journal-article","created":{"date-parts":[[2026,2,8]],"date-time":"2026-02-08T13:29:36Z","timestamp":1770557376000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Polyvinyl Chloride\u2010Derived Organosulfur Cathodes for Durable Li\u2013S 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