{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T21:34:38Z","timestamp":1792100078131,"version":"4.4.0"},"reference-count":83,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T00:00:00Z","timestamp":1771372800000},"content-version":"am","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T00:00:00Z","timestamp":1771372800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T00:00:00Z","timestamp":1771372800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["DE250100132"],"award-info":[{"award-number":["DE250100132"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,2,25]]},"abstract":"<jats:p>\n                    Lithium\u2010ion batteries (LIBs) and sodium\u2010ion batteries (SIBs) help meet the growing global demand for sustainable energy storage due to their high energy density, portability, and rechargeability. As a key component of secondary battery systems, the anode material largely determines their overall performance. However, commercial graphite is limited by its low theoretical capacity (372\u2009mAh\u00b7g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and poor Na\n                    <jats:sup>+<\/jats:sup>\n                    storage capacity, necessitating the exploration of alternative anode materials. Among the numerous candidate materials, iron\u2010based compounds (including oxides, sulfides, and porous materials derived from metal\u2013organic frameworks (MOFs)) stand out due to their high theoretical specific capacity, natural abundance, and environmental friendliness. However, severe volume expansion and structural instability during repeated charge\u2013discharge cycles lead to rapid capacity decay, severely hindering their practical application. This review systematically summarizes the recent progress in iron\u2010based compounds as anodes for LIBs and SIBs. The electrochemical properties of iron oxides, iron sulfides, and porous iron\u2010based derivatives are highlighted, with particular attention paid to the challenges posed by volume expansion. Furthermore, a comprehensive analysis of the strategies developed to mitigate volume expansion, such as nanostructure design, carbon composites, hollow\/porous structure engineering, and interface optimization, is presented. Finally, current limitations and future research opportunities are outlined, aiming to provide guidance for the rational design of high\u2010performance iron\u2010based anode materials for next\u2010generation rechargeable batteries.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502590","type":"journal-article","created":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T01:10:06Z","timestamp":1771463406000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Iron\u2010Based Materials for Advanced Lithium\/Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"19","author":[{"given":"Jianfeng","family":"Hou","sequence":"first","affiliation":[{"name":"Department of Chemical and Material Engineering Lyuliang University  Lvliang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0928-1673","authenticated-orcid":false,"given":"Xihan","family":"Tan","sequence":"additional","affiliation":[{"name":"Department of Chemical and Material Engineering Lyuliang University  Lvliang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Honglei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Nottingham Ningbo China Beacons of Excellence Research and Innovation Institute Department of Chemical and Environmental Engineering The University of Nottingham Ningbo China  Ningbo China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Han","sequence":"additional","affiliation":[{"name":"The Edward S. 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