{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T16:54:57Z","timestamp":1773420897248,"version":"3.50.1"},"reference-count":38,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T00:00:00Z","timestamp":1772928000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T00:00:00Z","timestamp":1772928000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379054"],"award-info":[{"award-number":["22379054"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22502229"],"award-info":[{"award-number":["22502229"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,3,13]]},"abstract":"<jats:p>\n                    Current synthetic methodologies for\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010hydroxy carboxylic acids are constrained by stringent reaction conditions and laborious product separation processes. To address these limitations, a Zn\/Ag catalyst was prepared via a pH\u2010regulated electrodeposition strategy in this study. By leveraging the bimetallic synergistic effect, the catalyst modulates the adsorption and activation of substrates, thereby promoting the electrochemical carboxylation of carbonyl compounds with CO\n                    <jats:sub>2<\/jats:sub>\n                    . The results showed that the Zn\/Ag catalyst achieved a high yield of 83% in the conversion of acetophenone to atrolactic acid. Infrared spectroscopy analyses verified that the reaction mechanism proceeds via a Zn\u2010Ag synergistic effect, which activates acetophenone to form a radical anion intermediate. This intermediate subsequently undergoes carboxylation with CO\n                    <jats:sub>2<\/jats:sub>\n                    , followed by an electron transfer step, to afford atrolactic acid with excellent selectivity. The catalyst facilitated the synthesis of 1.3\u2009g of carboxylated product from acetophenone and enabled the extension of electrocarboxylation to diverse substrates, including aryl ketones, aryl aldehydes, and aliphatic ketones. This work not only provides an efficient and cost\u2010effective route for the synthesis of\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010hydroxy carboxylic acids but also validates its potential for industrial\u2010scale application.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202502631","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:19:03Z","timestamp":1773026343000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Zn\u2010Ag Nanocatalysts Enable Electrochemical Carboxylation of Carbonyl Compounds With CO\n                    <sub>2<\/sub>\n                    for\n                    <i>\u03b1<\/i>\n                    \u2010Hydroxy Carboxylic Acids Synthesis"],"prefix":"10.1002","volume":"19","author":[{"given":"Chenxing","family":"Zhu","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological 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