{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T15:50:20Z","timestamp":1791993020257,"version":"4.4.0"},"reference-count":48,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T00:00:00Z","timestamp":1776297600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,4,28]]},"abstract":"<jats:p>\n                    The search for nontoxic and stable alternatives to halide perovskites has driven significant research into lead\u2010free double perovskite compositions. Among these, layered variants offer unique properties, but their synthesis often relies on solvent or heat\u2010intensive methods. Herein, we demonstrate a scalable and solvent\u2010free mechanochemical approach for the synthesis of \u27e8111\u27e9\u2010oriented layered double perovskites (LDPs). Three distinct solid solutions, Cs\n                    <jats:sub>4<\/jats:sub>\n                    Cu\n                    <jats:sub>\n                      1\u2212\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Mn\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Sb\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>12<\/jats:sub>\n                    , Cs\n                    <jats:sub>4<\/jats:sub>\n                    Cd\n                    <jats:sub>\n                      1\u2212\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Mn\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Sb\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>12<\/jats:sub>\n                    and Cs\n                    <jats:sub>4<\/jats:sub>\n                    Cd\n                    <jats:sub>\n                      1\u2212\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Mn\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Bi\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>12<\/jats:sub>\n                    (\n                    <jats:italic>x<\/jats:italic>\n                    \u2009=\u20090\u20131), were successfully obtained in batch sizes of up to 5.0\u2009g. All compounds can be obtained in less than 30\u2009min and retain their expected optical properties, highlighting mechanochemistry as a green and scalable route to lead\u2010free layered perovskites.\n                  <\/jats:p>","DOI":"10.1002\/cssc.202600004","type":"journal-article","created":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T06:06:29Z","timestamp":1776405989000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Mechanochemical Synthesis of Lead\u2010Free Halide Layered Double Perovskites: A Green and Scalable Approach"],"prefix":"10.1002","volume":"19","author":[{"given":"Teresa Ixchel","family":"Escobedo\u2010Perez","sequence":"first","affiliation":[{"name":"Laboratorio de Fisicoqu\u00edmica y Reactividad de Superficies (LaFReS), Universidad Nacional Aut\u00f3noma de M\u00e9xico Instituto de Investigaciones en Materiales  Ciudad de Mexico Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rafael","family":"Osorio\u2010Sotelo","sequence":"additional","affiliation":[{"name":"Laboratorio de Fisicoqu\u00edmica y Reactividad de Superficies (LaFReS), Universidad Nacional Aut\u00f3noma de M\u00e9xico Instituto de Investigaciones en Materiales  Ciudad de Mexico Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2486-0967","authenticated-orcid":false,"given":"Diego","family":"Solis\u2010Ibarra","sequence":"additional","affiliation":[{"name":"Laboratorio de Fisicoqu\u00edmica y Reactividad de Superficies (LaFReS), Universidad Nacional Aut\u00f3noma de M\u00e9xico Instituto de Investigaciones en Materiales  Ciudad de Mexico Mexico"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,4,16]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c04149"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2018.12.054"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c01867"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010022\u201005541\u2010z"},{"key":"e_1_2_9_6_1","first-page":"2025","article-title":"Interactive Best Research\u2010Cell Efficiency Chart","volume":"16","author":"National Renewable Energy Laboratory (NREL)","year":"2024","journal-title":"Accessed December"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00539"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.9b00454"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b04021"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201803150"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b04119"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.0c02912"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c03167"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b02099"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c04919"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307441"},{"key":"e_1_2_9_17_1","volume-title":"CrystalMaker","author":"Palmer D. C.","year":"2014"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/d0nr06771g"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c02684"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/d1nr06200j"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202500179"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201902499"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI00163F"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056571\u2010w"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/d3ra01692g"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/c5gc01008j"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3MR00018D"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202300819"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4MR90021A"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202100478"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trechm.2021.02.008"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1515\/ci\u20102019\u20100203"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA04904K"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b06788"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b05209"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b09160"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.8b19002"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mssp.2025.109678"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1088\/2515\u20107655\/ab155b"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c02054"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/c9nr06092h"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01255"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201800635"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202000162"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adem.202400636"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202007350"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202300261"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.isci.2019.05.042"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c00454"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202600004","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.202600004","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.202600004","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T15:28:05Z","timestamp":1791991685000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.202600004"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,4,16]]},"references-count":48,"journal-issue":{"issue":"8","published-print":{"date-parts":[[2026,4,28]]}},"alternative-id":["10.1002\/cssc.202600004"],"URL":"https:\/\/doi.org\/10.1002\/cssc.202600004","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,4,16]]},"assertion":[{"value":"2026-01-08","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-18","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-04-16","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202600004"}}