{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T10:08:19Z","timestamp":1784887699616,"version":"3.55.0"},"reference-count":47,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T00:00:00Z","timestamp":1778544000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,12]],"date-time":"2026-05-12T00:00:00Z","timestamp":1778544000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,5,14]]},"abstract":"<jats:p>\n                    Electrochemical reduction of carbon dioxide into multi\u2010carbon products provides a scheme to synthesize high value\u2010added feedstocks and carbon\u2010based fuels via renewable electricity, which has attracted wide attention. At present, Cu is one of the promising materials for electro\u2010catalyzing CO\n                    <jats:sub>2<\/jats:sub>\n                    to multi\u2010carbon products. However, the product distribution of Cu catalysts is relatively wide. Here, boron (B)\u2010doped Cu nanoparticles (NPs) with plentiful defects is prepared, which synergistic effects work together to regulate the local environment on the electrode surface, thereby effectively promoting the reduction of carbon dioxide to multicarbon (C\n                    <jats:sub>2+)<\/jats:sub>\n                    products in the neutral electrolyte. Especially, the enhanced local environment increases the *CO intermediate and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    adsorption, which in turn reduces the energy barrier of the C\uf8ffC coupling step. The results reveal that C\n                    <jats:sub>2+<\/jats:sub>\n                    Faradaic efficiency (FE) of boron\u2010doped Cu NPs (B\u2013Cu\u20131) is approximately 75% and the stability is up to 30\u2009h at \u22121.1\u2009V (vs. RHE). Density functional theory calculations further make it clear that the B\u2010induced defects and Cu\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    increase the adsorption of *CO intermediate, favoring the C\n                    <jats:sub>2+<\/jats:sub>\n                    pathways. This work paves a simple and effective method for promoting C\n                    <jats:sub>2+<\/jats:sub>\n                    production through double tuning of the local environment during CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR).\n                  <\/jats:p>","DOI":"10.1002\/cssc.202600013","type":"journal-article","created":{"date-parts":[[2026,5,13]],"date-time":"2026-05-13T03:26:56Z","timestamp":1778642816000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Double Tuning of the Local Environment on Cu Nanoparticles Towards Enhanced C\n                    <sub>2+<\/sub>\n                    Selectivity"],"prefix":"10.1002","volume":"19","author":[{"given":"Chunge","family":"Li","sequence":"first","affiliation":[{"name":"Zhengzhou Normal University  Zhengzhou 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