{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T15:50:44Z","timestamp":1791993044868,"version":"4.4.0"},"reference-count":63,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2026,4,21]],"date-time":"2026-04-21T00:00:00Z","timestamp":1776729600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,4,21]],"date-time":"2026-04-21T00:00:00Z","timestamp":1776729600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100010193","name":"KEPCO","doi-asserted-by":"publisher","award":["R23XO05\u201006"],"award-info":[{"award-number":["R23XO05\u201006"]}],"id":[{"id":"10.13039\/501100010193","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,4,28]]},"abstract":"<jats:p>\n                    Since Cu\u2010ZnO\u2010based catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol are generally suffered from thermal aggregations of Cu nanoparticles under an excess water environment, SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010encapsulated Cu\u2010ZnO\u2010based nanoparticles with multicore\u2013shell structures were applied in this study. The synergistic effects of In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    on the Cu\u2010ZnO surfaces and protective SiO\n                    <jats:sub>2<\/jats:sub>\n                    overlayers were verified to explain the positive contributions of In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    with decreased CO selectivity and an increased methanol selectivity above 80%, which were attributed to the prohibited competitive reverse water\u2013gas shift reaction activity and less aggregation nature of active metal (oxides) by SiO\n                    <jats:sub>2<\/jats:sub>\n                    shells. The increased oxygen vacant sites from partially reduced In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    , ZnO and Cu\n                    <jats:sup>n+<\/jats:sup>\n                    phases and larger surface area of metallic Cu\n                    <jats:sup>0<\/jats:sup>\n                    surfaces on the Cu\u2010ZnO\u2010In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    @SiO\n                    <jats:sub>2<\/jats:sub>\n                    were responsible for an enhanced CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion (25.3%) and methanol selectivity (80.1%) by easily activating CO\n                    <jats:sub>2<\/jats:sub>\n                    dissociation and suppressing RWGS reaction. To verify overall reaction mechanisms on the In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    metal oxide\u2010substituted Cu nanoparticles, Gibbs free energy diagrams for formyl, formate, and carboxyl intermediates pathways were compared by Density functional theory calculations, which revealed that the most favorable pathway for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to CH\n                    <jats:sub>3<\/jats:sub>\n                    OH was CHO\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sup>*<\/jats:sup>\n                    intermediate\u2010based formyl pathway on In\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2010substituted Cu(111) surfaces by decreasing CO selectivity due to the suppressed RWGS reaction activity.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70634","type":"journal-article","created":{"date-parts":[[2026,4,22]],"date-time":"2026-04-22T00:18:44Z","timestamp":1776817124000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol on Core\u2013Shell\u2010Structured SiO\n                    <sub>2<\/sub>\n                    \u2010Encapsulated Cu\u2010ZnO\u2010In\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Nanoparticles"],"prefix":"10.1002","volume":"19","author":[{"given":"Min Jung","family":"Park","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University (SKKU)  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hwi Yeon","family":"Woo","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University (SKKU)  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jae Hyeon","family":"Kwon","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Sungkyunkwan University (SKKU)  Suwon Gyeonggi\u2010do Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuna","family":"Song","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Yeungnam University  Gyeongsan Gyeongbuk Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seong jun","family":"Lee","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Yeungnam University  Gyeongsan Gyeongbuk Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Byoung\u2010Whan","family":"Soh","sequence":"additional","affiliation":[{"name":"MPIOS Inc.  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