{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,24]],"date-time":"2026-07-24T11:45:12Z","timestamp":1784893512842,"version":"3.55.0"},"reference-count":48,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Science Foundation of China","doi-asserted-by":"publisher","award":["52201158"],"award-info":[{"award-number":["52201158"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003787","name":"Hebei Provincial Natural Science Foundation of China","doi-asserted-by":"publisher","award":["B2024202016"],"award-info":[{"award-number":["B2024202016"]}],"id":[{"id":"10.13039\/501100003787","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,5,27]]},"abstract":"<jats:p>\n                    Zinc (Zn) is an attractive electrocatalyst for converting CO\n                    <jats:sub>2<\/jats:sub>\n                    to carbon monoxide (CO) via the carbon dioxide reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR), but its application is limited by poor selectivity and stability. In contrast to conventional crystalline modifiers or bulk buffers, we report a bifunctional strategy using an amorphous phosphate layer to simultaneously enhance proton transfer and stabilize Zn active sites. Amorphous phosphate\u2010modified zinc nanoflakes (Zn\u2010HPO\n                    <jats:sub>4<\/jats:sub>\n                    NF) were synthesized through a simple two\u2010step method. At \u22121.3\u2009V versus RHE, the Zn\u2010HPO\n                    <jats:sub>4<\/jats:sub>\n                    catalyst delivers a CO Faradaic efficiency (FE\n                    <jats:sub>CO<\/jats:sub>\n                    ) of 86.4%. The catalyst exhibits exceptional durability at \u22121.4V versus RHE, sustaining a stable current of\u2009~17 mA over 20\u2009h with an average FE\n                    <jats:sub>CO<\/jats:sub>\n                    exceeding 80% and negligible current decay, significantly outperforming pure Zn. In situ spectroscopy and operando electrochemical impedance spectroscopy reveal that amorphous hydrogen phosphate (HPO\n                    <jats:sub>4<\/jats:sub>\n                    <jats:sup>2\u2010<\/jats:sup>\n                    ) modification promotes the adsorption of key intermediates (*CO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2\u2010<\/jats:sup>\n                    and *COOH), facilitates efficient proton transfer through the establishment of an ordered hydrogen\u2010bonding network (consistent with the Grotthuss mechanism), and stabilizes\u00a0Zn active sites by acting as a buffer to regulate the local pH environment. These effects collectively enhance the stability and catalytic performance of the catalyst during CO\n                    <jats:sub>2<\/jats:sub>\n                    RR.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70648","type":"journal-article","created":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T09:01:26Z","timestamp":1778835686000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Bifunctional Amorphous Phosphate Layer Simultaneously Boosts Proton Transfer and Stabilizes Zn Active Sites for Efficient CO\n                    <sub>2<\/sub>\n                    RR"],"prefix":"10.1002","volume":"19","author":[{"given":"Yunjia","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Hebei University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7695-8037","authenticated-orcid":false,"given":"Jingjing","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Hebei University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinli","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Hebei University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingqian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of New\u2010Energy Materials School of Materials Science and Engineering Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengfei","family":"Yin","sequence":"additional","affiliation":[{"name":"Institute of New\u2010Energy Materials School of Materials Science and Engineering Tianjin University  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boxiong","family":"Shen","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Hebei University of Technology  Tianjin China"},{"name":"School of Energy and Environmental Engineering Hebei University of Technology  Tianjin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3624-1618","authenticated-orcid":false,"given":"Lang","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering Hebei University of Technology  Tianjin 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