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Herein, we report the elusive conversion of inorganic metal carbonates, such as sodium and potassium carbonates, to methanol in a one\u2010step process with molecular hydrogen over a heterogeneous Cu\/ZnO\/Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst. The hydrogenation occurs effectively at a relatively mild temperature of 200\u00b0C and proceeds in presence of ethylene glycol in the liquid phase with methanol yields of up to 95%. Alkali carbonates\/bicarbonate salts obtained by capturing CO\n                    <jats:sub>2<\/jats:sub>\n                    from ambient air (Direct Air Capture, DAC) and flue gas CO\n                    <jats:sub>2<\/jats:sub>\n                    with aqueous alkali media also undergo facile hydrogenation to methanol.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70665","type":"journal-article","created":{"date-parts":[[2026,4,27]],"date-time":"2026-04-27T00:05:02Z","timestamp":1777248302000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Direct Conversion of Metal Carbonates and Bicarbonates to Methanol Over a Cu\/ZnO\/Al\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>\n                    Catalyst"],"prefix":"10.1002","volume":"19","author":[{"given":"Christopher J.","family":"Koch","sequence":"first","affiliation":[{"name":"Loker Hydrocarbon Research Institute Department of Chemistry and Department of Chemical Engineering and Materials Science University of Southern California  Los Angeles California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7992-3956","authenticated-orcid":false,"given":"Raktim","family":"Sen","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute Department of Chemistry and Department of Chemical Engineering and Materials Science University of Southern California  Los Angeles California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9339-7814","authenticated-orcid":false,"given":"Anushan","family":"Alagaratnam","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute Department of Chemistry and Department of Chemical Engineering and Materials Science University of Southern California  Los Angeles California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8667-8530","authenticated-orcid":false,"given":"Alain","family":"Goeppert","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute Department of Chemistry and Department of Chemical Engineering and Materials Science University of Southern California  Los Angeles California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vicente","family":"Galvan","sequence":"additional","affiliation":[{"name":"Loker Hydrocarbon Research Institute Department of Chemistry and Department of Chemical Engineering and Materials Science University of Southern California  Los Angeles California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6350-8325","authenticated-orcid":false,"given":"G. 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