{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T12:08:37Z","timestamp":1779883717858,"version":"3.53.1"},"reference-count":33,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T00:00:00Z","timestamp":1778803200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000923","name":"Australian Research Council","doi-asserted-by":"publisher","award":["CE230100017"],"award-info":[{"award-number":["CE230100017"]}],"id":[{"id":"10.13039\/501100000923","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012659","name":"Foundation for Innovative Research Groups of the National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22368034"],"award-info":[{"award-number":["22368034"]}],"id":[{"id":"10.13039\/501100012659","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004479","name":"Jiangxi Natural Science Foundation","doi-asserted-by":"publisher","award":["20224BAB203021"],"award-info":[{"award-number":["20224BAB203021"]}],"id":[{"id":"10.13039\/501100004479","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,5,27]]},"abstract":"<jats:p>\n                    The construction of a stable Cu\n                    <jats:sup>+<\/jats:sup>\n                    \/Cu\n                    <jats:sup>0<\/jats:sup>\n                    reaction interface is a promising yet challenging strategy for the electrosynthesis of multicarbon (C\n                    <jats:sub>2+<\/jats:sub>\n                    ) products from CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction. Herein, we report a dual\u2010phase Cu\n                    <jats:sub>2<\/jats:sub>\n                    O\/Cu catalyst encapsulated by boron (B)\u2010doped carbon coatings (BC), denoted as Cu\n                    <jats:sub>2<\/jats:sub>\n                    O(Cu)@BC. In a flow cell system with 1\u2009M KOH electrolyte, this catalyst delivers a maximum C\n                    <jats:sub>2+<\/jats:sub>\n                    Faradaic efficiency of 83.4% at \u22120.7\u2009V versus the reversible hydrogen electrode (RHE) and a partial C\n                    <jats:sub>2+<\/jats:sub>\n                    current density of 460\u2009mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at \u22120.9\u2009V versus RHE, while maintaining stable operation for over 42\u2009h. This performance surpasses that of its counterpart without the BC coatings and other Cu\u2010based catalyst systems. Comprehensive experimental investigations reveal that the BC coatings facilitate the formation of Cu\n                    <jats:sup>+<\/jats:sup>\n                    species with higher oxidation states and stabilize the Cu\n                    <jats:sup>+<\/jats:sup>\n                    \/Cu\n                    <jats:sup>0<\/jats:sup>\n                    interface under reductive conditions. The resulting abundant and stable interfacial sites significantly increase *CO intermediate surface coverage, facilitating carbon\u2013carbon coupling and promoting the formation of the key *OCH\n                    <jats:sub>2<\/jats:sub>\n                    CH\n                    <jats:sub>3<\/jats:sub>\n                    intermediate for C\n                    <jats:sub>2+<\/jats:sub>\n                    production. This work offers an effective strategy to maintain a high density of Cu\n                    <jats:sup>+<\/jats:sup>\n                    \/Cu\n                    <jats:sup>0<\/jats:sup>\n                    interfacial active sites and provides deeper insights into the stabilization and degradation mechanisms of Cu\u2010based catalysts for efficient electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010to\u2010C\n                    <jats:sub>2+<\/jats:sub>\n                    conversion.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70731","type":"journal-article","created":{"date-parts":[[2026,5,15]],"date-time":"2026-05-15T08:47:49Z","timestamp":1778834869000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Boron\u2010Doped Carbon Coatings Stabilize Cu\n                    <sup>+<\/sup>\n                    \/Cu\n                    <sup>0<\/sup>\n                    Interfaces to Promote Multicarbon Formation in CO\n                    <sub>2<\/sub>\n                    Electroreduction"],"prefix":"10.1002","volume":"19","author":[{"given":"Haoming","family":"Yu","sequence":"first","affiliation":[{"name":"School of Chemistry Monash University  Clayton Australia"},{"name":"School of Chemistry and Chemical Engineering Nanchang University  Nanchang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengyu","family":"Hua","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanchang University  Nanchang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Zhu","sequence":"additional","affiliation":[{"name":"The Melbourne Centre of Nanofabrication in the Victorian Node of the Australian National Fabrication Facility  Clayton Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1302-826X","authenticated-orcid":false,"given":"Fangqi","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tonglin","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute of Advanced Materials (IAM) Nanjing University of Posts &amp; Telecommunications  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5176-309X","authenticated-orcid":false,"given":"Jun","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Nanchang University  Nanchang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2493-5209","authenticated-orcid":false,"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry Monash University  Clayton Australia"},{"name":"ARC Research Hub for Carbon Utilisation and Recycling Monash University  Clayton Australia"},{"name":"ARC Centre of Excellence for Green Electrochemical Transformation of Carbon Dioxide Monash University  Clayton Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,15]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00459"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00705"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE01301H"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202403217"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202313028"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202015159"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE01325E"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105118"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2023.08.027"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-018-0092-x"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00887H"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2026.126701"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1080\/01614940.2025.2453714"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202209629"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c02465"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c02451"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA11604A"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.3c01901"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00514"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404123"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c04589"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407748"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201700759"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c06697"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac248"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02428"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016898"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2418144122"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-024-49247-4"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-025-00868-7"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01579"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004846"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c09661"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70731","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.70731","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70731","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T11:49:36Z","timestamp":1779882576000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.70731"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,15]]},"references-count":33,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2026,5,27]]}},"alternative-id":["10.1002\/cssc.70731"],"URL":"https:\/\/doi.org\/10.1002\/cssc.70731","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,15]]},"assertion":[{"value":"2026-03-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication 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