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In this work, inspired by the hierarchical coupling of vascular and neural networks in biological systems, we report a high\u2010performance HER electrocatalyst consisting of platinum nanoparticles anchored on crisscross carbon micro\u2013nanostructures (CCMN). The 3D scaffold simultaneously accelerates charge delivery, proton supply, and hydrogen bubble detachment, thus alleviating key limitations in the electrode process. The Pt\/WC\/CCMN (2\u2009wt%) catalyst was prepared via controlled carburization of a W\u2010doped Fe\u2010BTC precursor, followed by selective Pt deposition through galvanic replacement. Electrochemical measurements reveal that the catalyst delivers 100\u2009mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at an overpotential of only 49\u2009mV. H\n                    <jats:sub>2<\/jats:sub>\n                    bubbles formed on the Pt\/WC\/CCMN electrode are relatively large and detach easily from the surface. Notably, Pt\/WC\/CCMN exhibits a turnover frequency value of 27.16\u2009H\n                    <jats:sub>2<\/jats:sub>\n                    \u2009s\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100\u2009mV, 3.6 times higher than that of commercial Pt\/C (7.41\u2009H\n                    <jats:sub>2<\/jats:sub>\n                    \u2009s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This work develops a competitive HER electrocatalyst and also provides a universal design strategy for gas\u2010involved electrocatalytic reactions.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70732","type":"journal-article","created":{"date-parts":[[2026,5,19]],"date-time":"2026-05-19T18:48:46Z","timestamp":1779216526000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Engineering Oriented Pt Deposition via Micro\u2013Nano Crisscross Scaffolds: A Paradigm for High\u2010Efficiency HER Catalyst"],"prefix":"10.1002","volume":"19","author":[{"given":"Zhaoyang","family":"Chen","sequence":"first","affiliation":[{"name":"International Sci. &amp; Tech. Cooperation Base of Energy Materials and Application, College of Chemical Engineering Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Zheng","sequence":"additional","affiliation":[{"name":"International Sci. &amp; Tech. Cooperation Base of Energy Materials and Application, College of Chemical Engineering Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahao","family":"Shao","sequence":"additional","affiliation":[{"name":"International Sci. &amp; Tech. Cooperation Base of Energy Materials and Application, College of Chemical Engineering Zhejiang University of Technology  Hangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengming","family":"Zhao","sequence":"additional","affiliation":[{"name":"International Sci. &amp; Tech. 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