{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T12:08:26Z","timestamp":1779883706674,"version":"3.53.1"},"reference-count":42,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2026,5,25]],"date-time":"2026-05-25T00:00:00Z","timestamp":1779667200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,5,25]],"date-time":"2026-05-25T00:00:00Z","timestamp":1779667200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100022972","name":"SEI","doi-asserted-by":"publisher","award":["SEIU202321"],"award-info":[{"award-number":["SEIU202321"]}],"id":[{"id":"10.13039\/100022972","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"Chinese National Science Foundation","doi-asserted-by":"publisher","award":["U22A20393"],"award-info":[{"award-number":["U22A20393"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,5,27]]},"abstract":"<jats:p>\n                    A series of zinc\u2010acetate\u2010triazolato catalysts (Zn(OAc)ATZ, Zn(OAc)TZ, Zn(OAc)TRZ, ATZ\u2009=\u20093\u2010amino\u20101,2,4\u2010triazolate, TZ\u2009=\u20091,2,4\u2010triazolate, TRZ\u2009=\u20095\u2010aminotetrazole) were developed for the direct synthesis of alkyl carbamates and corresponding alcohols from ammonia and dialkyl carbonates. Among them, Zn(OAc)ATZ exhibited exceptional catalytic performance due to its high surface area (441.11\u2009m\n                    <jats:sup>2<\/jats:sup>\n                    \/g), hierarchical porosity, and appropriate coordination environment. Under optimized conditions, 89% conversion of diethyl carbonate (DEC) with 88% ethyl carbamate (EC) yield could be achieved over Zn(OAc)ATZ at 80\u00b0C for 16\u2009h. For dimethyl carbonate (DMC), a remarkable 98% conversion and 97% methyl carbamate (MC) yield were obtained at 30\u00b0C within 6\u2009h, while dibutyl carbonate (DBC) required 24\u2009h at 90\u00b0C to reach 95% conversion and 93% butyl carbamate (BC) yield. Characterization of XPS and FT\u2010IR revealed that the synergistic interaction between Zn\u2013N bonds and carboxylate groups stabilized the active sites, enabling efficient substrate activation. The catalyst retained\u2009&gt;87% activity after three cycles, demonstrating excellent stability in alkaline ammonia environments. This work provides a sustainable and industrially viable strategy for alkyl carbamate synthesis, aligning with green chemistry principles and the \u201cdual\u2010carbon\u201d agenda.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70739","type":"journal-article","created":{"date-parts":[[2026,5,25]],"date-time":"2026-05-25T11:36:14Z","timestamp":1779708974000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Green Synthesis of Alkyl Carbamates via Non\u2010Phosgene Process From Reactions of NH\n                    <sub>3<\/sub>\n                    and Dialkyl Carbonate Over Zn\u2010Acetate\u2010Triazolato Catalysts"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1030-2649","authenticated-orcid":false,"given":"Peixue","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"},{"name":"Qingdao Center of Resource Chemistry &amp; New Materials  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjing","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1846-0403","authenticated-orcid":false,"given":"Shimin","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuchao","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"},{"name":"Qingdao Center of Resource Chemistry &amp; New Materials  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3656-1139","authenticated-orcid":false,"given":"Xinjiang","family":"Cui","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"},{"name":"Qingdao Center of Resource Chemistry &amp; New Materials  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5665-4933","authenticated-orcid":false,"given":"Feng","family":"Shi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou China"},{"name":"Qingdao Center of Resource Chemistry &amp; New Materials  Qingdao China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,5,25]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr60237a002"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf00077a044"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00521-016-2291-y"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00521-016-2253-4"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00521-016-2181-3"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie8003732"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NJ05757G"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1RA01386F"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2017.07.022"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jenvman.2018.12.013"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2009.01.031"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CY00131A"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2011.01.030"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2008.08.020"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2012.12.022"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201600745"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5RA14528G"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2011.04.008"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ05675K"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal8120579"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/ceat.200401911"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5GC01007A"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2022.112900"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6GC02509A"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11164-017-3030-4"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/b915023b"},{"key":"e_1_2_10_28_1","unstructured":"C.Xu L.Jiang andM.Xian Environmentally Friendly Synthesis Method of Carbamate 2021 CN Patent 112481319 B."},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00374H"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.9b01499"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.1051816jes"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202412402"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202100240"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909046"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200139g"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-017-2055-z"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/b413334j"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.6b00225"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC01157G"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2008.05.007"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0gc00536c"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201601878"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/cbh2.70022"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70739","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.70739","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70739","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T11:50:04Z","timestamp":1779882604000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.70739"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,5,25]]},"references-count":42,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2026,5,27]]}},"alternative-id":["10.1002\/cssc.70739"],"URL":"https:\/\/doi.org\/10.1002\/cssc.70739","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,5,25]]},"assertion":[{"value":"2026-02-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-05","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-05-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70739"}}