{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T09:08:52Z","timestamp":1784020132360,"version":"3.55.0"},"reference-count":51,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T00:00:00Z","timestamp":1782691200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T00:00:00Z","timestamp":1782691200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,7,14]]},"abstract":"<jats:p>\n                    Nano\u2010confined interfacial NHC\u2010Al sites in Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    \u2010supported ionic liquid phases (SILPs) act as engineered catalysts for selective CO\n                    <jats:sub>2<\/jats:sub>\n                    fixation into epoxides, with NHC\u2010Al adduct formation confirmed by solid\u2010state nuclear magnetic resonance (NMR)\u00a0and X\u2010ray photoelectron spectroscopy (XPS). The synergistic combination of NHC\u2010Al adducts and IL moieties generates membrane\u2010like nano\u2010confined environments at the solid\u2013liquid interface. These confined environments regulate substrate access and product diffusion during CO\n                    <jats:sub>2<\/jats:sub>\n                    absorption and fixation, which exhibit a high affinity for CO\n                    <jats:sub>2<\/jats:sub>\n                    capture under mild reaction conditions. Size\u2010selective transport within the nano\u2010confined SILP architecture favors small\u2010sized epoxides over bulky ones, leading to enhanced reaction rates and selectivity. The NHC@SILP\u2010PMImAl\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst, containing a lower fraction of NHC\u2010Al adduct (15%) and a high proportion of imidazolium\u2010chloride ion pairs, exhibited the highest activity, achieving a turnover frequency of 16.09\u2009h\n                    <jats:sup>\u22121<\/jats:sup>\n                    for epichlorohydrin at 1\u2010bar CO\n                    <jats:sub>2<\/jats:sub>\n                    and 70\u00b0C. In contrast, the NHC\u2010Al SILPs with a high NHC\u2010Al adduct (41%) showed a significantly reduced performance (59.1 TONs). This comparison highlights that catalytic efficiency is governed by a balance between NHC\u2010Al formation and the availability of nucleophilic chloride species within the nano\u2010confined environment. Chloride\u2010assisted CO\n                    <jats:sub>2<\/jats:sub>\n                    cycloaddition in SILPs proceeds via Al\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    surface hydroxyl\u2010mediated epoxide activation rather than imidazolium C2\u2010H pathways typical of neat ionic liquids, as supported by density functional theory.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70822","type":"journal-article","created":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T18:01:05Z","timestamp":1782756065000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nano\u2010Confined NHC\u2013Al Interfaces for Efficient CO\n                    <sub>2<\/sub>\n                    Chemical Fixation"],"prefix":"10.1002","volume":"19","author":[{"given":"Blendo A.","family":"da Silva","sequence":"first","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jonas","family":"Xavier","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Camila P.","family":"Ebersol","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vinicius K.","family":"Tomazett","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luiz H. K. Queiroz","family":"J\u00fanior","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fl\u00e1vio O.","family":"Sanches\u2010Neto","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heibbe Cristhian B.","family":"de Oliveira","sequence":"additional","affiliation":[{"name":"Instituto de Qu\u00edmica Universidade Federal de Goi\u00e1s\u2010UFGAv.  Goi\u00e2nia Goi\u00e1s Brazil"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Francisco P.","family":"dos Santos","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Universidade Federal do Rio Grande do Sul\u2010UFRGSAv.  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