{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,14]],"date-time":"2026-07-14T09:08:47Z","timestamp":1784020127225,"version":"3.55.0"},"reference-count":52,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2026,7,5]],"date-time":"2026-07-05T00:00:00Z","timestamp":1783209600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,5]],"date-time":"2026-07-05T00:00:00Z","timestamp":1783209600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS\u20102024\u201000348694"],"award-info":[{"award-number":["RS\u20102024\u201000348694"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS\u20102024\u201000303685"],"award-info":[{"award-number":["RS\u20102024\u201000303685"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,7,14]]},"abstract":"<jats:p>\n                    Rational design strategies for developing advanced electrocatalysts that replace the kinetically sluggish oxygen evolution reaction with the more thermodynamically favorable ethanol oxidation offer an effective pathway toward energy\u2010efficient hydrogen production. Herein, we strategically integrate NiSe\n                    <jats:sub>2<\/jats:sub>\n                    (NS) and CuFeO\n                    <jats:sub>2<\/jats:sub>\n                    (CFO) microstructures over biomass\u2010derived nitrogen\u2010doped carbonized wood (NCW) to construct a 3D, binder\u2010free, and bifunctional NS\u2010CFO@NCW electrode with a hierarchically interconnected heterostructure. The fusion of CFO cubes into the rough NS spheres establishes a strong interfacial interaction between the two components, which not only amplifies beneficial structural modulations but also tailors the electronic framework of Ni to equip the catalytically dynamic high\u2010valence phase. Benefiting from synergistic architecture, NS\u2010CFO@NCW exhibits superior ethanol oxidation reaction performance, delivering enhanced current density and favorable kinetics compared to its counterparts. When assembled into a bifunctional ethanol electrolyzer, the optimized NS\u2010CFO@NCW achieves an elevated current density of 100\u2009mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at a cell voltage of 1.63\u2009V, representing a 190\u2009mV reduction compared with that of standard water splitting, highlighting its remarkable energy efficiency. This work provides a sustainable design paradigm for coupling biomass upgrading with efficient hydrogen generation through advanced catalyst design and engineering.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70862","type":"journal-article","created":{"date-parts":[[2026,7,6]],"date-time":"2026-07-06T06:42:26Z","timestamp":1783320146000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hierarchically Engineered NiSe\n                    <sub>2<\/sub>\n                    \u2010CuFeO\n                    <sub>2<\/sub>\n                    Heterostructures on Biomass\u2010Derived Carbonized Wood for Efficient Ethanol\u2010Assisted Water Electrolysis"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8848-1261","authenticated-orcid":false,"given":"Ameer","family":"Farithkhan","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"},{"name":"Institute of Materials Technology Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seo\u2010Jun","family":"Lee","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alireza","family":"Razazzadeh","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"N. S. Krishnan","family":"Gowthaman","sequence":"additional","affiliation":[{"name":"Center for Advanced Energy Materials SRM TRP Engineering College  Tiruchirappalli Tamil Nadu India"},{"name":"Centre for Research Trichy SRM Medical College Hospital and Research Center  Tiruchirappalli Tamil Nadu India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Myung\u2010Jin","family":"Jung","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhou","family":"Qi","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2286-1824","authenticated-orcid":false,"given":"Se\u2010Hun","family":"Kwon","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Pusan National University  Busan Republic of Korea"},{"name":"Institute of Materials Technology Pusan National University  Busan Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,5]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202502000"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202405008"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201802011"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-022-00933-2"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202107548"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c00894"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.est.2024.112601"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306108"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202301165"},{"key":"e_1_2_9_11_1","first-page":"558","article-title":"Alkaline Water Electrolysis for Green Hydrogen Production","volume":"57","author":"T\u00fcys\u00fcz H.","year":"2023","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5c01897"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202002453"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202010437"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.76158"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122388"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.horiz.2021.100002"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00588"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01435"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja205649z"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CY00277F"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2024.115225"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202510285"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12678-019-00531-8"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b01800"},{"key":"e_1_2_9_26_1","first-page":"27033","article-title":"Structure and Catalysis of NiOOH: Recent Advances on Atomic Simulation","volume":"125","author":"Li Y. 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