{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T05:06:24Z","timestamp":1784696784963,"version":"3.55.0"},"reference-count":43,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T00:00:00Z","timestamp":1783555200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:p>\n                    Achieving the exposure of high\u2010energy active crystal planes is a very challenging issue due to the thermodynamic limitations. Herein, Pd nanosheets with exposed high\u2010energy (1\u201310) crystal planes were constructed on IRMOF via layer\u2010by\u2010layer (LBL) electrodeposition. The metal\u2013organic framework (MOF) matrix prevents Pd nanosheets aggregation through spatial isolation, while Pd\u2500N bonds with \u2500NH\n                    <jats:sub>2<\/jats:sub>\n                    groups in IRMOF stabilize the high\u2010energy Pd (1\u201310) crystal planes, enabling their continued activity under acidic hydrogen evolution reaction (HER) conditions. Benefiting from the intrinsically favorable hydrogen adsorption thermodynamics of the Pd (1\u201310) crystal plane and the high density of low\u2010coordination Pd sites, the optimized Pd\/IRMOF\u20103 achieves an ultralow overpotential of 15 and 370\u2009mV at 10 and 1000\u2009mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , respectively, outperforming commercial Pt\/C. Moreover, it exhibits outstanding durability, sustaining HER for 320\u2009h at 10\u2009mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , accompanied by preserved crystallinity and surface chemistry after long\u2010term HER. This work demonstrates that MOF\u2010stabilized Pd nanosheets with exposed active crystal planes offer a design for achieving simultaneously high activity and long\u2010term stability of electrocatalysts, providing insights for the rational construction of next\u2010generation electrocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70881","type":"journal-article","created":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T08:09:57Z","timestamp":1783584597000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["MOF\u2010Stabilized Pd Nanosheets With Exposed Active Crystal Planes for Efficient Hydrogen Evolution"],"prefix":"10.1002","volume":"19","author":[{"given":"Ning","family":"Song","sequence":"first","affiliation":[{"name":"Institute of Green Chemistry and Chemical Technology School of Chemistry and Chemical Engineering Jiangsu University  Zhenjiang P. R. 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