{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,19]],"date-time":"2026-10-19T23:31:11Z","timestamp":1792452671207,"version":"4.5.0"},"reference-count":47,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T00:00:00Z","timestamp":1785715200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T00:00:00Z","timestamp":1785715200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["No. 2023YFB3710401"],"award-info":[{"award-number":["No. 2023YFB3710401"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,8,14]]},"abstract":"<jats:p>\n                    Atomically dispersed nitrogen\u2010coordinated iron single atoms on carbon (FeN\n                    <jats:sub>4<\/jats:sub>\n                    SACs) stand out as highly promising non\u2010precious metal catalysts for the air cathode of zinc\u2010air batteries (ZABs). Herein, we improve bifunctional catalytic performance by uniformly anchoring FeCo nanoparticles onto a 3D cubic FeN\n                    <jats:sub>4<\/jats:sub>\n                    substrate through internal vapor\u2010phase etching and surface confinement engineering. In alkaline electrolyte, Fe\n                    <jats:sub>1<\/jats:sub>\n                    Co\n                    <jats:sub>1<\/jats:sub>\n                    @FeNC delivers exceptional bifunctionality with an ORR E\n                    <jats:sub>1\/2<\/jats:sub>\n                    of 0.904\u2009V and an OER overpotential of 308\u2009mV at 10\u2009mA\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The catalyst also exhibits excellent long\u2010term cycling stability, with only a negligible\n                    <jats:italic>E<\/jats:italic>\n                    <jats:sub>1\/2<\/jats:sub>\n                    decay of 18\u2009mV after 10,000 consecutive cycles. Notably, Fe\n                    <jats:sub>1<\/jats:sub>\n                    Co\n                    <jats:sub>1<\/jats:sub>\n                    @FeNC\u2010based ZABs deliver a peak power density of 167.67\u2009mW\u2009cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and over 600\u2009h of cycling stability, outperforming benchmark Pt\/C\u2009+\u2009RuO\n                    <jats:sub>2<\/jats:sub>\n                    . Density functional theory (DFT) reveals that the synergy between FeCo nanoparticles and Fe single atoms promotes interfacial electron transfer and downshifts the Fe d\u2010band center. This modulates the electronic configuration and weakens *OH binding, optimizing intermediate adsorption energies to significantly boost the intrinsic bifunctional activity.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70886","type":"journal-article","created":{"date-parts":[[2026,8,3]],"date-time":"2026-08-03T17:44:31Z","timestamp":1785779071000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["ZIF\u2010Derived FeCo Nanoparticles and FeN\n                    <sub>4<\/sub>\n                    Single\u2010Atom Sites for High\u2010Performance Oxygen Evolution and Oxygen Reduction Bifunctional Electrocatalysis"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-5665-2549","authenticated-orcid":false,"given":"Lin","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Electromagnetic Processing of Materials Ministry of Education Northeastern University  Shenyang China"},{"name":"School of Materials Science and Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lizi","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Electromagnetic Processing of Materials Ministry of Education Northeastern University  Shenyang China"},{"name":"School of Materials Science and Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Electromagnetic Processing of Materials Ministry of Education Northeastern University  Shenyang China"},{"name":"School of Materials Science and Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyu","family":"Li","sequence":"additional","affiliation":[{"name":"Key Laboratory of Electromagnetic Processing of Materials Ministry of Education Northeastern University  Shenyang China"},{"name":"School of Materials Science and Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Hu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Electromagnetic Processing of Materials Ministry of Education Northeastern University  Shenyang China"},{"name":"School of Materials Science and Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cong","family":"Han","sequence":"additional","affiliation":[{"name":"College of Resources and Civil Engineering Northeastern University  Shenyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,3]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13807-w"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202400881"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4738"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.1c01493"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.123695"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151987"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.102972"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3SE01238G"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2024.08.262"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2025.164273"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SE00586G"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202510985"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2023.143417"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2024.177754"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2023.06.016"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-018-0164-8"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201800441"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2022.101086"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2021.230891"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01640"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135320"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA08616A"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202107225"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2023.10.098"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215400"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b04105"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI02228A"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-019-0350-5"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2025.01.064"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC06197J"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b01563"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202510621"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja310566z"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5b00991"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202313028"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.12.029"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.02.080"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.2c03623"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c03823"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129938"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2023.06.007"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202009197"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2019.109568"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.03.054"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad0832"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307297"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2025.114374"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70886","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.70886","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.70886","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T13:43:22Z","timestamp":1786542202000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.70886"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,3]]},"references-count":47,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2026,8,14]]}},"alternative-id":["10.1002\/cssc.70886"],"URL":"https:\/\/doi.org\/10.1002\/cssc.70886","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,3]]},"assertion":[{"value":"2026-03-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-26","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-03","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e70886"}}