{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,22]],"date-time":"2026-07-22T05:05:59Z","timestamp":1784696759724,"version":"3.55.0"},"reference-count":24,"publisher":"Wiley","issue":"14","license":[{"start":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T00:00:00Z","timestamp":1784592000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T00:00:00Z","timestamp":1784592000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100014180","name":"Junta de Castilla y Le\u00f3n","doi-asserted-by":"publisher","award":["VA074G24"],"award-info":[{"award-number":["VA074G24"]}],"id":[{"id":"10.13039\/501100014180","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,7,29]]},"abstract":"<jats:p>\n                    In this work, we have developed a mild, metal\u2010free solution polycondensation protocol mediated by EDC and DMAP that enables the synthesis of bio\u2010based polyesters from thermally labile monomers while overcoming key limitations of high\u2010temperature melt polycondensation. We have prepared FDCA\u2010 and succinic acid\u2010based homopolyesters, revealing distinct structure\u2013property relationships between rigid furanic and flexible aliphatic systems. In addition, this methodology was extended to heteropolyesters via one\u2010pot and sequential strategies, enabling compositional control. Structure\u2013property relationships reveal that FDCA\u2010based furanic polyesters exhibit higher\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>g<\/jats:sub>\n                    values and predominantly amorphous character, whereas succinic\u2010acid\u2010based analogs show higher\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>onset<\/jats:sub>\n                    values and selective crystallinity. This library of polymers establishes EDC\/DMAP\u2010mediated polycondensation as a versatile platform for sustainable materials design beyond the limits of conventional melt processing.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70907","type":"journal-article","created":{"date-parts":[[2026,7,21]],"date-time":"2026-07-21T08:26:07Z","timestamp":1784622367000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Metal\u2010Free, Mild, and Sustainable Synthesis of Bio\u2010Based Polyesters via EDC\/DMAP\u2010Mediated Polycondensation: Structure\u2013Property Relationships and Thermal Stability"],"prefix":"10.1002","volume":"19","author":[{"given":"Luc\u00eda","family":"Pedraza","sequence":"first","affiliation":[{"name":"Department of Organic Chemistry Faculty of Science Campus Miguel Delibes University of Valladolid  Valladolid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Virginia","family":"Arn\u00e1iz","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Faculty of Science Campus Miguel Delibes University of Valladolid  Valladolid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mercedes","family":"Santiago\u2010Calvo","sequence":"additional","affiliation":[{"name":"Division of Transport and Energy Foundation for Transport and Energy Research and Development (CIDAUT) Parque Tecnol\u00f3gico de Boecillo  Valladolid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Javier","family":"Guerra","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Faculty of Science Campus Miguel Delibes University of Valladolid  Valladolid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Enol","family":"L\u00f3pez","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry School of Engineering (EII) University of Valladolid  Valladolid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Asunci\u00f3n","family":"Barbero","sequence":"additional","affiliation":[{"name":"Department of Organic Chemistry Faculty of Science Campus Miguel Delibes University of Valladolid  Valladolid 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