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One\u2010dimensional axially oriented superlattice Cd\n                    <jats:sub>0.6<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    S nanorods were prepared via a solvothermal method. The unique periodic arrangement of CdS and MnS units creates axial separation channels for electrons and holes, significantly reducing the bulk charge recombination rate. Subsequently, CuCoNiZnAlO high\u2010entropy oxide was successfully loaded onto the surface of Cd\n                    <jats:sub>0.6<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    S using a wet chemical precipitation method. Hydrogen evolution experiments demonstrate that the CC\u201015 composite catalyst exhibits 3.73 times the activity of pristine Cd\n                    <jats:sub>0.6<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    S. Experimental characterizations collectively confirm a substantial enhancement in photogenerated carrier separation efficiency within the CC\u201015 composite. Subsequently, in situ XPS and charge density difference analyses provide direct dynamic evidence, indicating the directional transfer of electrons from Cd\n                    <jats:sub>0.6<\/jats:sub>\n                    Mn\n                    <jats:sub>0.4<\/jats:sub>\n                    S to HEO under light illumination. This work offers a new perspective for replacing noble\u2010metal cocatalysts with transition\u2010metal\u2010based alternatives.\n                  <\/jats:p>","DOI":"10.1002\/cssc.70964","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T08:22:57Z","timestamp":1786954977000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["High\u2010Entropy Oxides Facilitated Heterojunction Engineering With Superlattice Cd\n                    <sub>0.6<\/sub>\n                    Mn\n                    <sub>0.4<\/sub>\n                    S for Enhanced Photocatalytic Hydrogen Evolution"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-2398-1407","authenticated-orcid":false,"given":"Jieyuan","family":"Du","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Ningxia Key Laboratory of Solar Chemical Conversion Technology Key Laboratory for Chemical Engineering and Technology State Ethnic Affairs Commission, North Minzu University  Yinchuan P. 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