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TMS based on mixtures of amines and carboxylic acids have been found to exhibit lower critical solution temperature (LCST) behavior, although prior examples have relied on clinical anesthetics as the amine component due to poor understanding of the relationship between the amine structure and LCST behavior. Here, the role of the amine partner of the TMS was systematically investigated, utilizing an array of primary, secondary, and tertiary amines in combination with aliphatic carboxylic acids. Systems featuring tripropylamine (TPA) or dibutylamine (DBA) were uniquely capable of displaying thermoswitchable behavior in the presence of a sufficiently hydrophobic aliphatic carboxylic acid, whereas primary amines and other secondary and tertiary amines investigated did not form TMS. TMS formation could be related to macroscopic hydrophilicity parameters for the amines, providing a foundational basis for future TMS design, and their ability to facilitate extractions was demonstrated. These findings highlight the potential to prepare TMS from scalable, low\u2010cost amines toward the development of environmentally benign switchable solvent systems.<\/jats:p>","DOI":"10.1002\/cssc.71019","type":"journal-article","created":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T13:36:23Z","timestamp":1787837783000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Structure\u2013Property Relationships for n\u2010Alkylamine and Aliphatic Carboxylic Acid\u2010Derived Thermomorphic Multiphase Systems"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-9115-2808","authenticated-orcid":false,"given":"Megha","family":"Thuruthel Kuriakose","sequence":"first","affiliation":[{"name":"School of Chemical Sciences University of Auckland  Auckland New Zealand"},{"name":"MacDiarmid Institute for Advanced Materials and Nanotechnology  Wellington New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2480-2959","authenticated-orcid":false,"given":"Kaveh","family":"Shahbaz","sequence":"additional","affiliation":[{"name":"College of Science and Engineering James Cook University  Townsville Australia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3626-7618","authenticated-orcid":false,"given":"Cameron C.","family":"Weber","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences University of Auckland  Auckland New Zealand"},{"name":"MacDiarmid Institute for Advanced Materials and Nanotechnology  Wellington New Zealand"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,27]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b918763b"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.crci.2018.03.010"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.7b00571"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3cs60241a"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0gc00797h"},{"key":"e_1_2_9_7_1","volume-title":"Green Chemistry : Theory and Practice","author":"Anastas P. 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