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Ruthenium catalysis using allyl alcohol or diallyl ether has been used to develop ready\u2010to\u2010graft allylic synthons based on glycerol carbonate and related derivatives. Allylated glycerol carbonate and glycidyl allyl ethers were thus used in effective ring\u2010opening reactions with high atom economy to convert Kraft, Organosolv, and Soda lignins without prior purification. Glycidyl allyl ethers were grafted onto lignin with a substitution degree of hydroxyl groups up to 90%. Technical and modified lignins were characterized by nuclear magnetic resonance (NMR), infrared (IR), size\u2010exclusion chromatography (SEC), and thermal properties were determined by differential scanning calorimetry (DSC). 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