{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T10:00:24Z","timestamp":1790416824362,"version":"4.1.0"},"reference-count":85,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T00:00:00Z","timestamp":1789862400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,20]],"date-time":"2026-09-20T00:00:00Z","timestamp":1789862400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100003052","name":"Ministry of Trade, Industry and Energy","doi-asserted-by":"publisher","award":["RS\u20102024\u201000436106"],"award-info":[{"award-number":["RS\u20102024\u201000436106"]}],"id":[{"id":"10.13039\/501100003052","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["RS\u20102025\u201025424498"],"award-info":[{"award-number":["RS\u20102025\u201025424498"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:p>\n                    Alkali\u2010metal amino acid solutions are attractive liquid sorbents for carbon capture. Potassium glycinate shows more favorable CO\n                    <jats:sub>2<\/jats:sub>\n                    capture behavior than sodium and lithium analogues despite sharing the same reactive amine motif. However, the molecular origin of this countercation effect remains unresolved. Here, we use molecular dynamics simulations to examine how K\n                    <jats:sup>+<\/jats:sup>\n                    , Na\n                    <jats:sup>+<\/jats:sup>\n                    , and Li\n                    <jats:sup>+<\/jats:sup>\n                    regulate CO\n                    <jats:sub>2<\/jats:sub>\n                    accessibility and transport in aqueous glycinate solutions. We treat CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake as a multistep process in which interfacial accessibility and transport precede chemical conversion, and we isolate this pre\u2010reactive stage. Li\n                    <jats:sup>+<\/jats:sup>\n                    forms a compact coordination environment with glycinate and water, restricting molecular mobility and reducing CO\n                    <jats:sub>2<\/jats:sub>\n                    access to glycinate\u2010centered regions. In contrast, K\n                    <jats:sup>+<\/jats:sup>\n                    maintains a more diffuse solvation environment, supporting higher diffusivities, larger interfacial CO\n                    <jats:sub>2<\/jats:sub>\n                    populations, and more frequent vapor\u2010to\u2010liquid transfer events. Collectively, these results identify interfacial gating, defined as cation\u2010dependent control of CO\n                    <jats:sub>2<\/jats:sub>\n                    population and exchange frequency at the vapor\u2013liquid boundary, as the interfacial manifestation of a cation\u2010controlled CO\n                    <jats:sub>2<\/jats:sub>\n                    accessibility mechanism around glycinate.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71069","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T06:19:54Z","timestamp":1789971594000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cation Effects on Pre\u2010Reactive CO\n                    <sub>2<\/sub>\n                    Accessibility and Interfacial Transfer in Aqueous Glycinate Solutions via Molecular Dynamics"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4550-2747","authenticated-orcid":false,"given":"Seungtae","family":"Kim","sequence":"first","affiliation":[{"name":"School of Chemical and Biological Engineering Institute of Chemical Processes Seoul National University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-5033-4740","authenticated-orcid":false,"given":"Minwoo","family":"Kim","sequence":"additional","affiliation":[{"name":"School of Chemical and Biological Engineering Institute of Chemical Processes Seoul National University  Seoul Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6629-277X","authenticated-orcid":false,"given":"Jee\u2010Eun","family":"Choi","sequence":"additional","affiliation":[{"name":"School of Chemical and Biological Engineering Institute of Chemical Processes Seoul National 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