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In this study, Cu\u2010core\/Pt\u2010shell modified SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    photocatalysts are demonstrated to enhance the thermally assisted photocatalytic methanol dehydrogenation in the gas phase by 50% compared to Pt\/SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    photocatalysts prepared by conventional photodeposition, while maintaining a high formaldehyde selectivity. Cu\u2010core\/Pt\u2010shell structures were prepared by means of galvanic displacement, in which Cu is displaced by Pt, yielding irregular core\u2013shell structures consisting of hexagonal Pt particles. These particles transform during extended operation into smooth core\u2013shell systems, thereby enabling stable methanol dehydrogenation. Initial deactivation of the samples is associated with CO\u2010induced Pt reconstruction, as evidenced by operando diffuse reflectance infrared Fourier transform spectroscopy and transmission electron microscopy. Despite this initial deactivation, the photocatalytic performance is found to be attributable to a significantly enhanced charge separation and carrier lifetime. This enhancement is presumed to be the result of the formation of an Ohmic contact between the SrTiO\n                    <jats:sub>3<\/jats:sub>\n                    absorber and Cu, thereby, enabling efficient charge transfer to the catalytically active Pt surface. This study underscores the beneficial properties of core\u2013shell cocatalysts and highlights the potential for value\u2010added chemical production using photocatalysis in the gas phase.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71077","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T03:01:45Z","timestamp":1790823705000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Decorating SrTiO\n                    <sub>3<\/sub>\n                    With Cu@Pt Core\u2010Shell Cocatalysts to Promote the Selective Thermally Assisted Photocatalytic Methanol Dehydrogenation to Formaldehyde"],"prefix":"10.1002","volume":"19","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3422-2491","authenticated-orcid":false,"given":"Yannik","family":"Haver","sequence":"first","affiliation":[{"name":"Laboratory of Industrial Chemistry Ruhr University Bochum  Bochum 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