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Lignocellulosic biomass (LCB) represents the largest natural carbon resource on the planet and is made up of cellulose, hemicellulose, and lignin, yet it is still primarily used for low\u2010value products. To advance the field, the capability of biomass as a feedstock for advanced materials necessitates viewing deconstruction and reconstruction not as distinct processes but as a unified, codesigned route. This review enhances that viewpoint by employing the \u201cdeconstruction\u2013reconstruction\u201d framework to link biomass fractionation with the potential products generated from it. We critically assess mild activation, component fractionation, and partial degradation through their ability to preserve the functional groups and structural motifs that govern downstream performance. Building on this, we map reconstruction pathways from biomass\u2010derived macromonomers into thermoplastics, thermosets, gel systems, vitrimeric elastomers, coatings, and adhesives. 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