{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T11:00:40Z","timestamp":1790420440307,"version":"4.1.0"},"reference-count":46,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T00:00:00Z","timestamp":1790380800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T00:00:00Z","timestamp":1790380800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22132001"],"award-info":[{"award-number":["22132001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:p>\n                    The practical application of aqueous zinc\u2010ion batteries (AZIBs) is severely limited by water\u2010induced issues, such as hydrogen evolution reaction, Zn metal corrosion, and cathode dissolution. To simultaneously stabilize the Zn anode and the NaV\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>8<\/jats:sub>\n                    (NVO) cathode, we propose a synergistic strategy based on mixed organic phosphate additives, which integrates triethyl phosphate (TEP) for bulk modulation and tris(2,2,2\u2010trifluoroethyl) phosphate (TFEP) for interfacial regulation. Experimental and computational investigations reveal that the TEP molecules actively participate in the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation sheath and disrupt the hydrogen\u2010bonding network of water. Meanwhile, the TFEP molecules preferentially adsorb onto the electrode surface and undergo reductive decomposition to construct a robust composite solid electrolyte interphase (SEI). The SEI, consisting of an inorganic\u2010rich inner layer and an organic\u2010rich outer layer, physically isolates the anode from active water and suppresses dendrite growth. Furthermore, the adsorbed TFEP contributes to the formation of a cathode electrolyte interphase (CEI) at the NVO cathode. Consequently, Zn||Zn symmetric cells achieve an extended cycling lifespan over 550\u2009h at 10\u2009mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 10 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and Zn||NVO full cells exhibit excellent cycling stability with 92.6 % capacity retention after 500 cycles at 1\u2009A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work provides a synergistic pathway for designing highly stable AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71091","type":"journal-article","created":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T10:11:02Z","timestamp":1790417462000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Interfacial and Bulk Modulation via Mixed Organic Phosphate Additives for Highly Stable Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"19","author":[{"given":"Tiantian","family":"Zhan","sequence":"first","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-6332-5752","authenticated-orcid":false,"given":"Zihao","family":"Wu","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuhui","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7010-038X","authenticated-orcid":false,"given":"Haotian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaodi","family":"Huang","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4959-6928","authenticated-orcid":false,"given":"Limin","family":"Qi","sequence":"additional","affiliation":[{"name":"Beijing National Laboratory for Molecular Sciences (BNLMS) College of Chemistry and Molecular Engineering, Peking University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,26]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aba4098"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2020.03.002"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.v37.48"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.v65.29"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2023.05.004"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12764"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.v16.24"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2023.109143"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CS01269D"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202501387"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE04847D"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2022.06.002"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.v36.14"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010026\u20103380\u20103"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v35.13"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010018\u20100063\u2010z"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00617"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.138265"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202418700"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010026\u201002148\u20107"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.101844"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.v10.3"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16880"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.v64.26"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.v35.18"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/smtd.v9.10"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2025.102269"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.v13.36"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v36.32"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426\u2010025\u20102874\u20105"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v35.6"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.v8.2"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.v35.20"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.v22.37"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.v13.22"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00942H"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.v35.24"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.v22.37"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v36.41"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE02164E"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v34.18"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v36.5"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.v63.50"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201004060\u20108"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.v36.32"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010026-02187-0"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.71091","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.71091","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.71091","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T10:11:02Z","timestamp":1790417462000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/cssc.71091"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,26]]},"references-count":46,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2026,10,14]]}},"alternative-id":["10.1002\/cssc.71091"],"URL":"https:\/\/doi.org\/10.1002\/cssc.71091","archive":["Portico"],"relation":{},"ISSN":["1864-5631","1864-564X"],"issn-type":[{"value":"1864-5631","type":"print"},{"value":"1864-564X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,26]]},"assertion":[{"value":"2026-07-10","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-09","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-26","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e71091"}}