{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T10:00:25Z","timestamp":1790416825003,"version":"4.1.0"},"reference-count":45,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities of China","doi-asserted-by":"publisher","award":["2572023CT10\u201005"],"award-info":[{"award-number":["2572023CT10\u201005"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,9,28]]},"abstract":"<jats:p>\n                    Manganese substitution can increase the practical capacities of NASICON\u2010type Na\n                    <jats:sub>3<\/jats:sub>\n                    V\n                    <jats:sub>2<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    \/C cathodes owing to the high Mn\n                    <jats:sup>2+<\/jats:sup>\n                    \/Mn\n                    <jats:sup>3+<\/jats:sup>\n                    activity and additional V\n                    <jats:sup>4+<\/jats:sup>\n                    \/V\n                    <jats:sup>5+<\/jats:sup>\n                    activation. However, these Mn\u2010substituted NASICON\u2010type cathodes generally suffer from low reaction kinetics and unsatisfactory rate capability. In this study, a Mn\/Al dual\u2010metal substitution strategy is utilized to design novel NASICON\u2010type cathodes with enhanced electrochemical performance by incorporating Al atoms into the Mn\u2010substituted Na\n                    <jats:sub>3.25<\/jats:sub>\n                    V\n                    <jats:sub>\n                      2.75\u2212\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Al\n                    <jats:sub>\n                      <jats:italic>x<\/jats:italic>\n                    <\/jats:sub>\n                    Mn\n                    <jats:sub>0.25<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )\n                    <jats:sub>3<\/jats:sub>\n                    \/C (NVAMP\/C, 0\u2009\u2264\u2009\n                    <jats:italic>x<\/jats:italic>\n                    \u2009\u2264\u20090.2) system. The influence of Al content on the structural and electrochemical properties of the designed NVAMP\/C materials is investigated by coupling various physical characterizations and electrochemical measurements. Experimental results reveal that the optimized NVAMP\/C composition not only shows greatly high practical capacities of 122.0\u2009mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10\u2009mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    and 103.5\u2009mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 1000\u2009mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , but also exhibits robust cycling stability with 81.8% retention after 500 cycles at 100\u2009mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, combined ex situ X\u2010ray diffraction, galvanostatic intermittent titration technique, and d\n                    <jats:italic>Q<\/jats:italic>\n                    \/d\n                    <jats:italic>V<\/jats:italic>\n                    analysis confirm that the Mn\/Al dual\u2010metal substitution regulates the phase\u2010evolution mechanism, thereby endowing the material with superior electrochemical reversibility and enhanced reaction kinetics. The finding suggests that the dual\u2010metal substitution strategy is effective in boosting the electrochemical properties of NASICON\u2010type cathodes for advanced sodium\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71094","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T03:47:16Z","timestamp":1790135236000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dual\u2010Metal Substitution Enabled NASICON\u2010Type Phosphate Cathodes With Enhanced Electrochemical Activity and Reaction Kinetics for Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"19","author":[{"given":"Ruonan","family":"Sun","sequence":"first","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Bai","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayong","family":"Lv","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayu","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinbiao","family":"Fu","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nan","family":"Sun","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5342-2835","authenticated-orcid":false,"given":"Xingde","family":"Xiang","sequence":"additional","affiliation":[{"name":"College of Chemistry &amp; Chemical Engineering and Resource Utilization Northeast Forestry University  Harbin 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