{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:59:38Z","timestamp":1790319578488,"version":"4.1.0"},"reference-count":50,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T00:00:00Z","timestamp":1790208000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemSusChem"],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"\n Photocatalytic H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production via a two\u2010electron oxygen reduction reaction (ORR) represents a green and sustainable alternative to the conventional anthraquinone process for industrial H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n synthesis. Bimetallic sulfide Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n has emerged as a promising photocatalyst for H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production, yet the efficiency remains to be promoted. In this work, we introduced an anionic surfactant, sodium dodecyl sulfate (SDS), into the hydrothermal reactant to achieve a surface\u2010modified Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n with a high photocatalytic H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production efficiency. The SDS modification alters the electron state and band alignments and promotes the formation of sulfur vacancies. Consequently, the SDS modification tactic not only enhances charge separation and migration but also switches the reaction pathway from an ORR\u2010dominated route in the pristine Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n to a dual\u2010pathway involving both ORR and water oxidation reaction (WOR). The optimized SDS0.5\u2010Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n photocatalyst achieves a remarkable H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production rate of 1066.13\u2009\u03bcmol\u00b7g\n \u22121<\/jats:sup>\n \u00b7h\n \u22121<\/jats:sup>\n in pure water without any sacrificial agents, which is 1.6 times that of the pristine Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n . Moreover, under argon atmosphere, it exhibits a H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production rate of 598.83\u2009\u03bcmol\u00b7g\n \u22121<\/jats:sup>\n \u00b7h\n \u22121<\/jats:sup>\n , approximately three times that of unmodified Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n , confirming the enhanced WOR contribution. This work presents a novel Zn\n 3<\/jats:sub>\n In\n 2<\/jats:sub>\n S\n 6<\/jats:sub>\n \u2010based photocatalyst with dual reaction pathways for efficient photocatalytic H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n production.\n <\/jats:p>","DOI":"10.1002\/cssc.71097","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:16:04Z","timestamp":1790316964000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Surface\u2010Modified Zn\n 3<\/sub>\n In\n 2<\/sub>\n S\n 6<\/sub>\n for a Dual\u2010Pathway Photocatalytic Hydrogen Peroxide Production"],"prefix":"10.1002","volume":"19","author":[{"given":"Guang","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University Hangzhou China"},{"name":"Zhejiang Provincial Engineering Research Center of Oxide Semiconductors for Environmental and Optoelectronic Applications Institute of Wenzhou, Zhejiang University Wenzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lisha","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zhejiang Provincial Engineering Research Center of Oxide Semiconductors for Environmental and Optoelectronic Applications Institute of Wenzhou, Zhejiang University Wenzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iram","family":"Hussain","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University Hangzhou China"},{"name":"Zhejiang Provincial Engineering Research Center of Oxide Semiconductors for Environmental and Optoelectronic Applications Institute of Wenzhou, Zhejiang University Wenzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0886-0115","authenticated-orcid":false,"given":"Zhizhen","family":"Ye","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University Hangzhou China"},{"name":"Zhejiang Provincial Engineering Research Center of Oxide Semiconductors for Environmental and Optoelectronic Applications Institute of Wenzhou, Zhejiang University Wenzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7157-8465","authenticated-orcid":false,"given":"Jin\u2010Ming","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University Hangzhou China"},{"name":"Zhejiang Provincial Engineering Research Center of Oxide Semiconductors for Environmental and Optoelectronic Applications Institute of Wenzhou, Zhejiang University Wenzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.161409"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c04797"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202522831"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.gee.2025.01.004"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064166\u20108"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.5c05354"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202512549"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047624\u20107"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202510644"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c07539"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c22625"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516678"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2026.126632"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201069549\u2010z"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201070161\u20104"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202509867"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511422"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmst.2025.04.030"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10390"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202302964"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506963"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201028686\u2010x"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.3c02866"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2024.12.003"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202406527"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.126071"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202521029"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202210110"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijhydene.2026.153717"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.3c01307"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2026.116724"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505046"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.3c00230"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.131192"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.renene.2026.125517"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ceramint.2024.09.360"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2011.02.062"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.3c02654"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2018.08.050"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2026.121239"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtphys.2024.101484"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00882E"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.144275"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.124436"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2020.118650"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202511687"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201026340\u20106"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202103715"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.5c06038"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.164909"}],"container-title":["ChemSusChem"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/cssc.71097","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/cssc.71097","content-type":"application\/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