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Herein, zinc pentafluorophenyl porphyrin (ZnPF) derivatives are developed as supramolecular passivators through\n                    <jats:italic>p<\/jats:italic>\n                    \u2010selective nucleophilic aromatic substitution and incorporated into perovskite films via a green anisole\u2010based antisolvent strategy. Systematic variation of the aromatic substituents provided insight into the relationship between molecular structure, supramolecular packing, and defect passivation. In particular, the\n                    <jats:italic>p<\/jats:italic>\n                    \u2010phenoxy substituent in ZnPF\u20102 balanced steric effects and promoted ordered molecular packing, leading to more effective interfacial passivation. This multifunctional passivation improved perovskite crystallinity and charge\u2010carrier transport while suppressing non\u2010radiative recombination and interfacial leakage currents. Consequently, ZnPF\u20102\u2010modified devices achieved a remarkable power conversion efficiency (PCE) of 34.29% under 1000\u2009lx illumination, while also showing consistent gains under AM 1.5G conditions and in a compositionally distinct perovskite system, supporting the transferability of the strategy. Moreover, the hydrophobic ZnPF modification improved long\u2010term durability, with devices preserving over 90% of their initial efficiency after 1600\u2009h under ambient storage. This work establishes supramolecular fluorinated porphyrins as effective passivators, demonstrating how rational molecular design can contribute to sustainable indoor photovoltaic applications.\n                  <\/jats:p>","DOI":"10.1002\/cssc.71098","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T06:14:43Z","timestamp":1790316883000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rational Supramolecular Design of Multifunctional Fluorinated Porphyrins for Efficient and Stable Indoor Carbon\u2010Based Perovskite Solar Cells"],"prefix":"10.1002","volume":"19","author":[{"given":"Araya","family":"Ruengsuk","sequence":"first","affiliation":[{"name":"Department of Physics and Materials Science Faculty of Science Chiang Mai University  Chiang Mai 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